Carbamazepine Adsorption onto Giant Macroporous Silica and Adaptive Neuro-Fuzzy Inference System Modeling

dc.authorid0000-0003-2734-8544
dc.authorid0000-0001-9760-9856
dc.authorid0000-0001-9943-771X
dc.authorid0000-0002-1628-5026
dc.authorid0000-0001-6954-2703
dc.authorid0000-0002-8440-2546
dc.contributor.authorAlver, Alper
dc.contributor.authorYılmaz, Bahar Akyüz
dc.contributor.authorBilican, Behlül Koç
dc.contributor.authorBaştürk, Emine
dc.contributor.authorKaya, Murat
dc.contributor.authorIşık, Mustafa
dc.date.accessioned2024-07-02T12:43:34Z
dc.date.available2024-07-02T12:43:34Z
dc.date.issued2024
dc.departmentTeknik Bilimler Meslek Yüksekokulu
dc.description.abstractThere is an imperative need to eliminate pharmaceutical residues from aquatic environments due to their hazardous properties, including toxicity, mutagenicity, and carcinogenicity, particularly when present in water sources. Conventional water treatment methods have proven insufficient in addressing nano-pollutants such as pharmaceutical residues. Consequently, the ongoing quest for economically viable, sustainable, and environmentally friendly removal mechanisms persists. In this particular study, we employed Giant Macroporous Silica (GMS) derived from marine sponges as a promising biosorbent. GMS exhibits commendable characteristics, including a high specific surface area, swift mass transfer capabilities, and non-discriminatory adsorption qualities. The efficacy of GMS in adsorbing carbamazepine (CBZ), a common drug residue, was scrutinized under diverse experimental conditions, including a sorbate/sorbent ratio ranging from 0.005 to 1.500 weight ratio, contact times spanning from 0 to 240 min, and initial pH values ranging from 5 to 9. Remarkably, at a concentration of 1000 µg L?1, GMS demonstrated an attractive adsorption rate (98.88%) of carbamazepine at pH 7.07, within 90 min. To enhance our understanding, we developed an ANFIS model utilizing the experimental parameters as inputs. The developed model exhibited a high correlation coefficient of 0.9944% and a root mean square error (RMSE) of 1.6693, indicating its dependability in accurately predicting the adsorption of CBZ on GMS. The results of our study highlight the efficacy of GMS in adsorbing CBZ, suggesting its considerable potential for adsorbing other pharmaceutical residues and nano-pollutants.
dc.identifier.doi10.1007/s13369-024-09032-3
dc.identifier.endpage8524en_US
dc.identifier.issn2193-567X
dc.identifier.issue6en_US
dc.identifier.scopusqualityQ1
dc.identifier.startpage8509en_US
dc.identifier.urihttps:/dx.doi.org/10.1007/s13369-024-09032-3
dc.identifier.urihttps://hdl.handle.net/20.500.12451/12021
dc.identifier.volume49en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer Nature
dc.relation.ispartofArabian Journal for Science and Engineering
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectAdaptive Neuro-Fuzzy Inference System
dc.subjectAdsorption
dc.subjectCarbamazepine
dc.subjectGiant Macroporous Silica
dc.subjectModeling
dc.titleCarbamazepine Adsorption onto Giant Macroporous Silica and Adaptive Neuro-Fuzzy Inference System Modeling
dc.typeArticle

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