An anomalous addition of chlorosulfonyl isocyanate to a carbonyl group: the synthesis of ((3aS, 7aR, E)-2-ethyl-3-oxo-2,3,3a, 4,7,7a-hexahydro-1H-isoindol-1-ylidene)sulfamoyl chloride

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dc.contributor.authorKöse, Aytekin
dc.contributor.authorÜnal, Aslı
dc.contributor.authorŞahin, Ertan
dc.contributor.authorBozkaya, UĞur
dc.contributor.authorKara, Yunus
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T09:16:21Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T09:16:21Z
dc.date.issued2019
dc.departmentSabire Yazıcı Fen Edebiyat Fakültesi
dc.description.abstractIn this study, we developed a new addition reaction of chlorosulfonyl isocyanate (CSI), starting from 2-ethyl-3a, 4,7,7a-tetrahydro-1H- isoindole-1,3(2H)-dione. The addition reaction of CSI with 2-ethyl-3a, 4,7,7a-tetrahydro-1H-isoindole-1,3(2H)-dione resulted in the formation of ylidenesulfamoyl chloride, whose exact configuration was determined by X-ray crystal analysis. We explain the mechanism of product formation supported by theoretical calculations.
dc.description.sponsorshipDepartment of Chemistry; Ataturk University; Scientific and Technological Research Council of Turkey [TUBITAK-116Z506]
dc.description.sponsorshipThe authors are indebted to Department of Chemistry and Ataturk University for financial support. This research was supported by the Scientific and Technological Research Council of Turkey (TUBITAK-116Z506).
dc.identifier.doi10.3762/bjoc.15.89
dc.identifier.endpage936en_US
dc.identifier.issn1860-5397
dc.identifier.pmid31164929
dc.identifier.scopusqualityQ2
dc.identifier.startpage931en_US
dc.identifier.urihttps://doi.org/10.3762/bjoc.15.89
dc.identifier.urihttps://hdl.handle.net/20.500.12451/4579
dc.identifier.volume15en_US
dc.identifier.wosWOS:000465322800001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherBeilstein-Institut
dc.relation.ispartofBeilstein Journal of Organic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectAddition Reaction
dc.subjectChlorosulfonyl Isocyanate
dc.subjectSulfamoyl Chloride
dc.subjectTheoretical Calculations
dc.titleAn anomalous addition of chlorosulfonyl isocyanate to a carbonyl group: the synthesis of ((3aS, 7aR, E)-2-ethyl-3-oxo-2,3,3a, 4,7,7a-hexahydro-1H-isoindol-1-ylidene)sulfamoyl chloride
dc.typeArticle

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