Strong Amphoteric Adsorption of Reactive Red-141 onto Modified Orange Peel Derivatives: Optimization, Characterization, and Mechanism

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Tarih

2025

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

MDPI

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

first_pagesettingsOrder Article Reprints Open AccessArticle Strong Amphoteric Adsorption of Reactive Red-141 onto Modified Orange Peel Derivatives: Optimization, Characterization, and Mechanism by Behlul Koc-Bilican 1ORCID,Ismail Bilican 2 andHakan Çelebi 3,*ORCID 1 Department of Molecular Biology and Genetics, Faculty of Science and Letters, Aksaray University, 68100 Aksaray, Türkiye 2 Department of Electronics and Automation, Technical Vocational School, Aksaray University, 68100 Aksaray, Türkiye 3 Department of Environmental Engineering, Faculty of Engineering, Aksaray University, 68100 Aksaray, Türkiye * Author to whom correspondence should be addressed. Polymers 2025, 17(13), 1875; https://doi.org/10.3390/polym17131875 Submission received: 2 June 2025 / Revised: 2 July 2025 / Accepted: 3 July 2025 / Published: 4 July 2025 (This article belongs to the Section Biobased and Biodegradable Polymers) Downloadkeyboard_arrow_down Browse Figures Versions Notes Abstract This study investigates the adsorption performance of Reactive Red-141 (ReR-141) using three modified orange peel derivatives: raw orange peel (ROP), oil-free orange peel (NOOP), and cellulose extract (CE). The adsorbents were prepared through sequential treatments and characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and Fourier-transform infrared spectroscopy to investigate their surface morphology and functional groups. Batch adsorption experiments were conducted under varying conditions of pH, temperature, time, and adsorbent amount. NOOP displayed the highest adsorption capacity (99.72% removal efficiency), followed by CE (86.99%) and ROP (77.55%), under optimal conditions. The adsorption kinetics followed a PSO model, while the equilibrium data were best described by Langmuir, indicating monolayer adsorption. Thermodynamic factors confirmed that the process was self-generated and primarily determined by physisorption. Desorption studies using 0.2 M NaOH demonstrated that NOOP retained 98.16% efficiency after three cycles, indicating its strong reusability. The adsorption mechanism is determined by different interactions, such as electrostatic forces, H-bonding, and π–π stacking. These findings suggest that orange peel derivatives, particularly NOOP, serve as optimal and environmentally sustainable adsorbents for the yield of ReR-141 from synthetic aqueous media.

Açıklama

Anahtar Kelimeler

Orange Peel Derivatives, Reactive Red-141, Sustainable Adsorbents

Kaynak

Polymers

WoS Q Değeri

Q1

Scopus Q Değeri

Cilt

17

Sayı

13

Künye