Hibiscus Rosasinensis L. aqueous extract-assisted valorization of lignin: Preparation of magnetically reusable Pd NPs@Fe3O4-lignin for Cr(VI) reduction and Suzuki-Miyaura reaction in eco-friendly media
| dc.authorid | 0000-0003-0206-3841 | |
| dc.contributor.author | Nasrollahzadeh, Mahmoud | |
| dc.contributor.author | Bidgoli, Nayyereh Sadat Soheili | |
| dc.contributor.author | Issaabadi, Zahra | |
| dc.contributor.author | Baran, Talat | |
| dc.contributor.author | Ghavamifar, Zahra | |
| dc.contributor.author | Luque, Rafael | |
| dc.date.accessioned | 2020-02-10T12:14:59Z | |
| dc.date.available | 2020-02-10T12:14:59Z | |
| dc.date.issued | 2020 | |
| dc.department | Sabire Yazıcı Fen Edebiyat Fakültesi | |
| dc.description | Baran, Talat ( Aksaray, Yazar ) | |
| dc.description.abstract | Hibiscus Rosasinensis L. extract mediated biosynthesis of Pd nanoparticles (NPs) and their deposition on the magnetic calcium lignosulfonate (MCaLig), as a simple and eco-friendly process for the preparation of Pd NPs@Fe3O4-lignin, is reported. The Pd NPs@Fe3O4-lignin was characterized by TEM, XRD, EDS, FE-SEM, FT-IR, VSM, and UV–Vis. The magnetic NPs were employed as exceptional catalysts in the catalytic reduction of Cr(VI) and Suzuki-Miyaura reaction between PhB(OH)2 and substituted aryl halides in EtOH:H2O as well as under ligand free conditions in the presence of K2CO3 with satisfactory product yields. Regeneration of the Pd NPs@Fe3O4-lignin was carried out by a magnet after the preparation of biphenyls. Catalytic efficiency retention was achieved after seven cycles. | |
| dc.identifier.endpage | - | en_US |
| dc.identifier.issue | - | en_US |
| dc.identifier.pmid | 31935407 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.startpage | - | en_US |
| dc.identifier.uri | https://hdl.handle.net/20.500.12451/7130 | |
| dc.identifier.volume | 148 | en_US |
| dc.identifier.wos | WOS:000522094600027 | |
| dc.identifier.wosquality | Q1 | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.indekslendigikaynak | PubMed | |
| dc.language.iso | en | |
| dc.publisher | Elsevier B.V. | |
| dc.relation.ispartof | International Journal of Biological Macromolecules | |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
| dc.rights | info:eu-repo/semantics/embargoedAccess | |
| dc.subject | Biowaste | |
| dc.subject | Cr(VI) Reduction | |
| dc.subject | Hibiscus | |
| dc.subject | Rosasinensis L. | |
| dc.subject | Pd NPs@Fe3O4-lignin | |
| dc.subject | Suzuki-Miyaura | |
| dc.title | Hibiscus Rosasinensis L. aqueous extract-assisted valorization of lignin: Preparation of magnetically reusable Pd NPs@Fe3O4-lignin for Cr(VI) reduction and Suzuki-Miyaura reaction in eco-friendly media | |
| dc.type | Article |
