A fluorescent hypochlorite probe built on 1,10-phenanthroline scaffold and its Ion recognition features

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dc.contributor.authorPamuk Algı, Melek
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-29T19:28:51Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-29T19:28:51Z
dc.date.issued2016
dc.departmentSabire Yazıcı Fen Edebiyat Fakültesi
dc.description.abstractIn this study, the synthesis of 7-((Hydroxyimino)methyl)-1,10-phenanthroline-4-carbaldehyde oxime (1) in two steps starting from 4,7-dimethyl-1,10-phenanthroline (2) is reported. It is found that compound 1 can be used as a fluorogenic probe for the detection of hypochlorite ion in aqueous solution. NMR and mass spectral analysis indicate that probe 1 undergoes a chemical transformation through its oxime units upon treatment with hypochlorite, which results in a remarkable enhancement of the emission intensity. Also, metal ion recognition properties of probe 1 is investigated. It is noted that compound 1 is responsive to Zn2+, Cd2+, Ni2+ and Cu2+ metal ions, which reduced the emission intensity under identical conditions.
dc.description.sponsorshipAksaray University [ASU BAP 2015-092]
dc.description.sponsorshipThe author is indebted to Aksaray University for partial financial support of this work (ASU BAP 2015-092).
dc.identifier.doi10.1007/s10895-015-1734-7
dc.identifier.endpage496en_US
dc.identifier.issn1053-0509
dc.identifier.issn1573-4994
dc.identifier.issue2en_US
dc.identifier.pmid26670687
dc.identifier.scopusqualityQ3
dc.identifier.startpage487en_US
dc.identifier.urihttps://doi.org/10.1007/s10895-015-1734-7
dc.identifier.urihttps://hdl.handle.net/20.500.12451/6094
dc.identifier.volume26en_US
dc.identifier.wosWOS:000371403000013
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherSpringer/Plenum Publishers
dc.relation.ispartofJournal of Fluorescence
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectFluorescence
dc.subjectProbe
dc.subjectHypochlorite
dc.subject1,10-phenanthroline
dc.titleA fluorescent hypochlorite probe built on 1,10-phenanthroline scaffold and its Ion recognition features
dc.typeArticle

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