Assembly of NHC-stabilized 2-hydrophosphasilenes from Si(iv) precursors: a Lewis acid-base complex

Basit Öğe Kaydı
dc.contributor.authorDhara, Debebrata
dc.contributor.authorMandal, Debdeep
dc.contributor.authorMaiti, Avijit
dc.contributor.authorYıldız, Cem Burak
dc.contributor.authorKalita, Pankaj
dc.contributor.authorChrysochos, Nicolas
dc.contributor.authorSchulzke, Carola
dc.contributor.authorChandrasekhar, Vadapalli
dc.contributor.authorJana, Anukul
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T08:22:02Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T08:22:02Z
dc.date.issued2016
dc.departmentAksaray Teknik Bilimler Meslek Yüksekokulu
dc.description.abstractNHC-stabilized 2-hydrophosphasilenes are obtained from 1,2-dihydro-2-chlorophosphasilanes as Si(iv) precursors by a NHC-assisted 1,2-elimination of HCl. The NHC-exchange of these compounds is demonstrated as a proof of donor acceptor bonding between NHC and the silicon centre of the “P” moiety. We have also explored the possibility of similar exchanges in NHC-stabilized Si2 and P2 compounds. Theoretical DFT calculations were performed to address the nature of Si-P bonding in the NHC-stabilized 2-hydrophosphasilenes. © The Royal Society of Chemistry.
dc.identifier.doi10.1039/C6DT04321F
dc.identifier.endpage19298en_US
dc.identifier.issn1477-9226
dc.identifier.issue48en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage19290en_US
dc.identifier.urihttps://dx.doi.org/10.1039/C6DT04321F
dc.identifier.urihttps://hdl.handle.net/20.500.12451/2441
dc.identifier.volume45en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofDalton Transactions
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.titleAssembly of NHC-stabilized 2-hydrophosphasilenes from Si(iv) precursors: a Lewis acid-base complex
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
yildiz-cem burak-2016.pdf
Boyut:
991.13 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin / Full Text
İndir

Koleksiyon

Makale Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu