Assembly of NHC-stabilized 2-hydrophosphasilenes from Si(iv) precursors: a Lewis acid-base complex
Yükleniyor...
Tarih
2016
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Royal Society of Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
NHC-stabilized 2-hydrophosphasilenes are obtained from 1,2-dihydro-2-chlorophosphasilanes as Si(iv) precursors by a NHC-assisted 1,2-elimination of HCl. The NHC-exchange of these compounds is demonstrated as a proof of donor acceptor bonding between NHC and the silicon centre of the “P” moiety. We have also explored the possibility of similar exchanges in NHC-stabilized Si2 and P2 compounds. Theoretical DFT calculations were performed to address the nature of Si-P bonding in the NHC-stabilized 2-hydrophosphasilenes. © The Royal Society of Chemistry.
Açıklama
Anahtar Kelimeler
Kaynak
Dalton Transactions
WoS Q Değeri
N/A
Scopus Q Değeri
Q2
Cilt
45
Sayı
48
