The oxidation state in low-valent beryllium and magnesium compounds
| dc.authorid | 0000-0001-5222-2201 | |
| dc.authorid | 0000-0002-0424-4673 | |
| dc.authorid | 0000-0002-9455-4906 | |
| dc.authorid | 0000-0002-1657-1321 | |
| dc.authorid | 0000-0003-1823-7295 | |
| dc.authorid | 0000-0003-2515-7859 | |
| dc.contributor.author | Gimferrer, Marti | |
| dc.contributor.author | Danes, Sergi | |
| dc.contributor.author | Vos, Eva | |
| dc.contributor.author | Yıldız, Cem Burak | |
| dc.contributor.author | Corral, Ines | |
| dc.contributor.author | Jana, Anukul | |
| dc.contributor.author | Salvador, Pedro | |
| dc.contributor.author | Andrada, Diego M. | |
| dc.date.accessioned | 2022-06-27T05:49:39Z | |
| dc.date.available | 2022-06-27T05:49:39Z | |
| dc.date.issued | 2022 | |
| dc.department | Teknik Bilimler Meslek Yüksekokulu | |
| dc.description.abstract | Low-valent group 2 (E = Be and Mg) stabilized compounds have been long synthetically pursued. Here we discuss the electronic structure of a series of Lewis base-stabilized Be and Mg compounds. Despite the accepted zero(0) oxidation state nature of the group 2 elements of some recent experimentally accomplished species, the analysis of multireference wavefunctions provides compelling evidence for a strong diradical character with an oxidation state of +2. Thus, we elaborate on the distinction between a description as a donor-acceptor interaction L(0) ? E(0) reversible arrow L(0) and the internally oxidized situation, better interpreted as a diradical L(-1) -> E(+2) <- L(-1) species. The experimentally accomplished examples rely on the strengthened bonds by increasing the pi-acidity of the ligand; avoiding this interaction could lead to an unprecedented low-oxidation state. | |
| dc.identifier.doi | 10.1039/d2sc01401g | |
| dc.identifier.endpage | 6591 | en_US |
| dc.identifier.issn | 2041-6520 | |
| dc.identifier.issn | 2041-6539 | |
| dc.identifier.issue | 22 | en_US |
| dc.identifier.pmid | 35756523 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.startpage | 6583 | en_US |
| dc.identifier.uri | https:/dx.doi.org/10.1039/d2sc01401g | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12451/9484 | |
| dc.identifier.volume | 13 | en_US |
| dc.identifier.wos | WOS:000797579700001 | |
| dc.identifier.wosquality | Q1 | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.indekslendigikaynak | PubMed | |
| dc.language.iso | en | |
| dc.publisher | The Royal Society of Chemistry | |
| dc.relation.ispartof | Chemical Science | |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
| dc.rights | info:eu-repo/semantics/closedAccess | |
| dc.subject | Bond | |
| dc.subject | Complexes | |
| dc.subject | Definition | |
| dc.subject | Orbitals | |
| dc.subject | Ligands | |
| dc.subject | Mg | |
| dc.title | The oxidation state in low-valent beryllium and magnesium compounds | |
| dc.type | Article |
