The oxidation state in low-valent beryllium and magnesium compounds
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Tarih
2022
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
The Royal Society of Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Low-valent group 2 (E = Be and Mg) stabilized compounds have been long synthetically pursued. Here we discuss the electronic structure of a series of Lewis base-stabilized Be and Mg compounds. Despite the accepted zero(0) oxidation state nature of the group 2 elements of some recent experimentally accomplished species, the analysis of multireference wavefunctions provides compelling evidence for a strong diradical character with an oxidation state of +2. Thus, we elaborate on the distinction between a description as a donor-acceptor interaction L(0) ? E(0) reversible arrow L(0) and the internally oxidized situation, better interpreted as a diradical L(-1) -> E(+2) <- L(-1) species. The experimentally accomplished examples rely on the strengthened bonds by increasing the pi-acidity of the ligand; avoiding this interaction could lead to an unprecedented low-oxidation state.
Açıklama
Anahtar Kelimeler
Bond, Complexes, Definition, Orbitals, Ligands, Mg
Kaynak
Chemical Science
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
13
Sayı
22
