Comparative experimental and theoretical studies of N-(4-ethylbenzylidene)-N'-(2-carboxyphenyl) hydrazine novel Schiff base

Basit Öğe Kaydı
dc.authoridÖzcelik, Nefise -- 0000-0002-6972-1071;
dc.contributor.authorTunç, Tuncay
dc.contributor.authorTezcan, Habibe
dc.contributor.authorSağlam, Semran
dc.contributor.authorÖzçelik, Nefise
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-29T19:29:32Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-29T19:29:32Z
dc.date.issued2014
dc.departmentEğitim Fakültesi Fen-Edebiyat Fakültesi
dc.description.abstractIn this work, N-(4-Methylbenzylidene)-N'-(2-carboxyphenyl) hydrazine, C15H14N2O2, Schiff base molecule has been synthesized and characterized by elemental analyses, UV-Vis and IR spectroscopy and single crystal X-ray determination. The molecule of the title compound adopt an E configuration about the azomethine C=N double bond. The benzene and phenyl rings are planar and the dihedral angle between the planes is 7.2(2)degrees. The crystal structure is stabilized by intermolecular O-H...O and intramoleculer N-H. ...O hydrogen bonding interactions. X-ray diffraction analyses show that, N-(4-Methylbenzylidene)-N'-(2-carboxyphenyl) hydrazine Schiff base molecule crystallizes in the monoclinic system, P2(1)/c space group, a = 4.392(5) angstrom, b = 22.340(5) angstrom, c = 13.528(5) angstrom, beta = 92.882(5), V= 1325.7(16) angstrom(3), Z= 4. The conformational analysis of N-(4-Methylbenzylidene)-N'-(2-carboxyphenyl) hydrazine was performed by the density functional theory (DFT) B3LYP method using the 6-311++G(d,p) basis set. Also, theoretical values of FTIR and UV-Vis were performed by the same method. The calculated geometry parameters, IR and UV-Vis results were compared with experimental results.
dc.identifier.doi10.1016/j.saa.2014.02.104
dc.identifier.endpage497en_US
dc.identifier.issn1386-1425
dc.identifier.pmid24657931
dc.identifier.scopusqualityQ1
dc.identifier.startpage490en_US
dc.identifier.urihttps://doi.org/10.1016/j.saa.2014.02.104
dc.identifier.urihttps://hdl.handle.net/20.500.12451/6180
dc.identifier.volume127en_US
dc.identifier.wosWOS:000336110500062
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherPergamon - Elsevier Science
dc.relation.ispartofSpectrochimica Acta Part A - Molecular and Biomolecular Spectroscopy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectHydrazone
dc.subjectCondensation Reaction
dc.subjectCrystal Structure
dc.subjectDFT
dc.titleComparative experimental and theoretical studies of N-(4-ethylbenzylidene)-N'-(2-carboxyphenyl) hydrazine novel Schiff base
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim
İsim:
tunc-tuncay-2014.pdf
Boyut:
859.51 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin / Full Text
İndir

Koleksiyon

Makale Koleksiyonu
Makale Koleksiyonu
PubMed İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu