Cationic palladium(II) catalysts on O-carboxymethyl chitosan schiff base for Suzuki coupling reactions

Basit Öğe Kaydı
dc.authoridBARAN, TALAT -- 0000-0003-0206-3841; MENTES, AYFER -- 0000-0003-3946-4075
dc.contributor.authorBaran, Talat
dc.contributor.authorMenteş, Ayfer
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-29T19:27:13Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-29T19:27:13Z
dc.date.issued2016
dc.departmentFen-Edebiyat Fakültesi
dc.description.abstractIn this study, catalytic activity of two different cationic O-Carboxymethyl chitosan Schiff base palladium (II) complexes in Suzuki coupling reactions and synthesis of biarlys having different functional groups, and reusability of the catalysts were tested. Chemical structures of the synthesized biaryls were elucidated by GC-MS and H-1-NMR; and no by-products were observed in the spectra. Cationic palladium (II) catalysts high turnover numbers and selectivity were recorded for the reactions. Mercury test demonstrated that the reaction mechanism proceed a homogeneous route. Reusability tests of cationic biocatalysts showed that their catalytic activity were still highly efficient even after six cycles.
dc.description.sponsorshipScientific and Technical Research Council of Turkey (TUBITAK) [113Z296]; Aksaray University Scientific Research Projects Coordination [201220]; Science and Technology Application and Research Center of Aksaray University, Turkey
dc.description.sponsorshipThis work was financial support by the Scientific and Technical Research Council of Turkey (TUBITAK; Project Number: 113Z296), Aksaray University Scientific Research Projects Coordination (Project Number: 201220). Science and Technology Application and Research Center of Aksaray University, Turkey.
dc.identifier.doi10.1080/10601325.2016.1224626
dc.identifier.endpage690en_US
dc.identifier.issn1060-1325
dc.identifier.issn1520-5738
dc.identifier.issue11en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage687en_US
dc.identifier.urihttps://doi.org/10.1080/10601325.2016.1224626
dc.identifier.urihttps://hdl.handle.net/20.500.12451/5817
dc.identifier.volume53en_US
dc.identifier.wosWOS:000385564600005
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherTaylor & Francis
dc.relation.ispartofJOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectBiopolymer
dc.subjectO-Carboxymethyl Chitosan Schiff Base
dc.subjectSuzuki Coupling Reaction
dc.subjectHomogeneous Catalyst
dc.titleCationic palladium(II) catalysts on O-carboxymethyl chitosan schiff base for Suzuki coupling reactions
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim
İsim:
talat-baran-2016.pdf
Boyut:
660.8 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin / Full Text
İndir

Koleksiyon

Makale Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu

We collect and process your personal information for the following purposes: Authentication, Preferences, Acknowledgement and Statistics.
To learn more, please read our privacy policy.

Customize