Cationic palladium(II) catalysts on O-carboxymethyl chitosan schiff base for Suzuki coupling reactions
Yükleniyor...
Dosyalar
Tarih
2016
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, catalytic activity of two different cationic O-Carboxymethyl chitosan Schiff base palladium (II) complexes in Suzuki coupling reactions and synthesis of biarlys having different functional groups, and reusability of the catalysts were tested. Chemical structures of the synthesized biaryls were elucidated by GC-MS and H-1-NMR; and no by-products were observed in the spectra. Cationic palladium (II) catalysts high turnover numbers and selectivity were recorded for the reactions. Mercury test demonstrated that the reaction mechanism proceed a homogeneous route. Reusability tests of cationic biocatalysts showed that their catalytic activity were still highly efficient even after six cycles.
Açıklama
Anahtar Kelimeler
Biopolymer, O-Carboxymethyl Chitosan Schiff Base, Suzuki Coupling Reaction, Homogeneous Catalyst
Kaynak
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY
WoS Q Değeri
N/A
Scopus Q Değeri
Q2
Cilt
53
Sayı
11
