Reduction of 2-H-substituted pyrrolinium cations: the carbon-carbon single bond in air stable 2,2?-bipyrrolidines as a two-electron-source

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dc.authorid0000-0003-1626-3502
dc.authorid0000-0002-4627-6905
dc.authorid0000-0002-7288-9238
dc.authorid0000-0002-5151-3987
dc.authorid0000-0002-7530-539X
dc.authorid0000-0002-0424-4673
dc.authorid0000-0002-1657-1321
dc.contributor.authorNayak, Mithilesh Kumar
dc.contributor.authorElvers, Benedict J.
dc.contributor.authorMandal, Debdeep
dc.contributor.authorDas, Ayan
dc.contributor.authorRamakrishnan, Raghunathan
dc.contributor.authorMote, Kaustubh R.
dc.contributor.authorSchulzke, Carola
dc.contributor.authorYıldız, Cem Burak
dc.contributor.authorJana, Anukul
dc.date.accessioned2023-10-04T06:09:58Z
dc.date.available2023-10-04T06:09:58Z
dc.date.issued2023
dc.departmentTeknik Bilimler Meslek Yüksekokulu
dc.description.abstractReduction of 2-H-substituted pyrrolinium cations via initially formed secondary radicals results in either dimerisation or H-abstracted products, while the outcome depends on the N-substituents. The resultant central carbon-carbon single bond in the dimerised 2,2?-bipyrrolidine derivatives can be oxidised chemically and electrochemically. The notably air and moisture-stable dimers were subsequently utilised as a source of two electrons in various chemical transformations.
dc.identifier.doi10.1039/d3cc00891f
dc.identifier.endpage6701en_US
dc.identifier.issn1359-7345
dc.identifier.issue44en_US
dc.identifier.pmid37183853
dc.identifier.scopusqualityQ1
dc.identifier.startpage6698en_US
dc.identifier.urihttps:/dx.doi.org10.1039/d3cc00891f
dc.identifier.urihttps://hdl.handle.net/20.500.12451/11061
dc.identifier.volume59en_US
dc.identifier.wosWOS:000987702700001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofChemical Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectReduction of 2-H-substituted Pyrrolinium
dc.titleReduction of 2-H-substituted pyrrolinium cations: the carbon-carbon single bond in air stable 2,2?-bipyrrolidines as a two-electron-source
dc.typeArticle

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