Reduction of 2-H-substituted pyrrolinium cations: the carbon-carbon single bond in air stable 2,2?-bipyrrolidines as a two-electron-source
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Tarih
2023
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Royal Society of Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Reduction of 2-H-substituted pyrrolinium cations via initially formed secondary radicals results in either dimerisation or H-abstracted products, while the outcome depends on the N-substituents. The resultant central carbon-carbon single bond in the dimerised 2,2?-bipyrrolidine derivatives can be oxidised chemically and electrochemically. The notably air and moisture-stable dimers were subsequently utilised as a source of two electrons in various chemical transformations.
Açıklama
Anahtar Kelimeler
Reduction of 2-H-substituted Pyrrolinium
Kaynak
Chemical Communications
WoS Q Değeri
Q2
Scopus Q Değeri
Q1
Cilt
59
Sayı
44
