Construction of new biopolymer (chitosan)-based pincer-type Pd(II) complex and its catalytic application in Suzuki cross coupling reactions

dc.authoridBARAN, TALAT -- 0000-0003-0206-3841
dc.contributor.authorBaran, Talat
dc.contributor.authorMenteş, Ayfer
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-29T19:26:38Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-29T19:26:38Z
dc.date.issued2017
dc.departmentFen-Edebiyat Fakültesi
dc.description.abstractIn this paper we described the fabrication, characterization and application of a new biopolymer (chitosan)-based pincer-type Pd(II) catalyst in Suzuki cross coupling reactions using a non-toxic, cheap, ecofriendly and practical method. The catalytic activity tests showed remarkable product yields as well as TON (19800) and TOF (330000) values with a small catalyst loading. In addition, the catalyst indicated good recyclability in the Suzuki C-C reaction. This biopolymer supported catalyst can be used with various catalyst systems due to its unique properties, such as being inert, green in nature, low cost and chemically durable.
dc.description.sponsorshipAksaray University Scientific Research Projects [2016-021]
dc.description.sponsorshipThe authors thank Aksaray University Scientific Research Projects Coordination for their financial support (Project Number: 2016-021).
dc.identifier.doi10.1016/j.molstruc.2017.01.005
dc.identifier.endpage598en_US
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopusqualityQ1
dc.identifier.startpage591en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.01.005
dc.identifier.urihttps://hdl.handle.net/20.500.12451/5664
dc.identifier.volume1134en_US
dc.identifier.wosWOS:000394919100067
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectBio-polymer
dc.subjectBiaryls
dc.subjectSchiff Base
dc.subjectMicrowave
dc.subjectReusability
dc.titleConstruction of new biopolymer (chitosan)-based pincer-type Pd(II) complex and its catalytic application in Suzuki cross coupling reactions
dc.typeArticle

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