Aquabis(3-chlorobenzoato-?O)bis(N,N-diethylnicotinamide-?N) copper(II)
| dc.contributor.author | Bozkurt, Nihat | |
| dc.contributor.author | Tunç, Tuncay | |
| dc.contributor.author | Çaylak Delibaş, Nagihan | |
| dc.contributor.author | Necefoğlu, Hacali | |
| dc.contributor.author | Hökelek, Tuncer | |
| dc.date.accessioned | 13.07.201910:50:10 | |
| dc.date.accessioned | 2019-07-16T08:22:55Z | |
| dc.date.available | 13.07.201910:50:10 | |
| dc.date.available | 2019-07-16T08:22:55Z | |
| dc.date.issued | 2013 | |
| dc.department | Eğitim Fakültesi | |
| dc.description.abstract | The title compound, [Cu(C7H4ClO2)2(C10H14N2O)2(H2O)], has twofold symmetry with the CuII cation and the O atom of the coordinating water molecule located on the axis. The CuII cation is coordinated by two carboxylate O atoms of chlorobenzoate (CB) anions, two N atoms of N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted N2O3 square-pyramidal geometry. The benzene and pyridine rings are oriented at a dihedral angle of 82.51 (6)°. In the anionic ligand, the carboxylate group is twisted away from the attached benzene ring by 12.85 (11)°. In the crystal, O - H?O hydrogen bonds between the coordinating water molecule and the carboxyl group link the complex molecules into supramolecular chains running along the c-axis direction. | |
| dc.identifier.doi | 10.1107/S1600536813018989 | |
| dc.identifier.endpage | m459 | en_US |
| dc.identifier.issn | 1600-5368 | |
| dc.identifier.issue | 8 | en_US |
| dc.identifier.scopusquality | N/A | |
| dc.identifier.startpage | m458 | en_US |
| dc.identifier.uri | https://dx.doi.org/10.1107/S1600536813018989 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12451/2670 | |
| dc.identifier.volume | 69 | en_US |
| dc.indekslendigikaynak | Scopus | |
| dc.language.iso | en | |
| dc.relation.ispartof | Acta Crystallographica Section E: Structure Reports Online | |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.subject | Data-to-Parameter Ratio = 27.8 | |
| dc.subject | Mean?(C - C) = 0.003 A ° | |
| dc.subject | Rfactor = 0.032 | |
| dc.subject | Single-crystal X-ray Study | |
| dc.subject | T = 296 K | |
| dc.subject | wRfactor = 0.086 | |
| dc.title | Aquabis(3-chlorobenzoato-?O)bis(N,N-diethylnicotinamide-?N) copper(II) | |
| dc.type | Article |
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