Aquabis(3-chlorobenzoato-?O)bis(N,N-diethylnicotinamide-?N) copper(II)
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Dosyalar
Tarih
2013
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The title compound, [Cu(C7H4ClO2)2(C10H14N2O)2(H2O)], has twofold symmetry with the CuII cation and the O atom of the coordinating water molecule located on the axis. The CuII cation is coordinated by two carboxylate O atoms of chlorobenzoate (CB) anions, two N atoms of N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted N2O3 square-pyramidal geometry. The benzene and pyridine rings are oriented at a dihedral angle of 82.51 (6)°. In the anionic ligand, the carboxylate group is twisted away from the attached benzene ring by 12.85 (11)°. In the crystal, O - H?O hydrogen bonds between the coordinating water molecule and the carboxyl group link the complex molecules into supramolecular chains running along the c-axis direction.
Açıklama
Anahtar Kelimeler
Data-to-Parameter Ratio = 27.8, Mean?(C - C) = 0.003 A °, Rfactor = 0.032, Single-crystal X-ray Study, T = 296 K, wRfactor = 0.086
Kaynak
Acta Crystallographica Section E: Structure Reports Online
WoS Q Değeri
Scopus Q Değeri
N/A
Cilt
69
Sayı
8
