A phosphorescent fluoride probe based on Eu(III)-DO3A clicked with a 2,5-di(thien-2-yl)pyrrole scaffold

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dc.authoridAlgi, Fatih -- 0000-0001-9376-1770
dc.contributor.authorBilmez, Memduh
dc.contributor.authorDeğirmenci, Aysun
dc.contributor.authorAlgı, Melek Pamuk
dc.contributor.authorAlgı, Fatih
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T09:14:52Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T09:14:52Z
dc.date.issued2018
dc.departmentSabire Yazıcı Fen Edebiyat Fakültesi
dc.description.abstractThe design, synthesis and physicochemical properties of a new phosphorescent fluoride probe 1 are described. The probe consists of a stable Eu(III) complex of a DO3A macrocycle on one side and a 2,5-di(thien-2-yl)pyrrole (SNS) scaffold on the other. They were linked together with a 1,2,3-triazole ring as a reliable connection unit, which was formed by Huisgen type copper-catalyzed [3+2] cycloaddition between the corresponding azide and alkyne. This novel material can be used as a turn-on phosphorescent fluoride probe. To the best of our knowledge, this is the first example of the combination of an SNS unit with a clicked Eu(III) complex of DO3A scaffold, which can induce a prominent luminogenic response to fluoride ions among other anions. Finally, its behavior as a two-input OR logic gate was also demonstrated using OH- and OAc- anions.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [112T668]; European Cooperation in Science and Technology (CMST COST Action European F-Element Network (EUFEN)) [CM 1006]; Turkish Academy of Sciences (TUBA) for an Outstanding Young Investigator Award (GEBIP); TUBITAK
dc.description.sponsorshipThe authors are grateful to the Scientific and Technological Research Council of Turkey (TUBITAK, Grant No. 112T668) and European Cooperation in Science and Technology (CMST COST Action CM 1006 European F-Element Network (EUFEN)). F. A. is indebted to the Turkish Academy of Sciences (TUBA) for an Outstanding Young Investigator Award (GEBIP). M. B. and A. D. are indebted to TUBITAK for graduate fellowships. F. A. thanks S. Ozcubukcu for providing a small amount of their click catalyst as a gift.
dc.identifier.doi10.1039/c7nj03569a
dc.identifier.endpage457en_US
dc.identifier.issn1144-0546
dc.identifier.issn1369-9261
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage450en_US
dc.identifier.urihttps://doi.org/10.1039/c7nj03569a
dc.identifier.urihttps://hdl.handle.net/20.500.12451/4186
dc.identifier.volume42en_US
dc.identifier.wosWOS:000418369000048
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherRoyal SOC Schemistry C
dc.relation.ispartofNew Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.titleA phosphorescent fluoride probe based on Eu(III)-DO3A clicked with a 2,5-di(thien-2-yl)pyrrole scaffold
dc.typeArticle

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