Synthesis, chemiluminescence and energy transfer efficiency of 2,3-dihydrophthalazine-1,4-dione and BODIPY dyad

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dc.authoridAlgi, Fatih -- 0000-0001-9376-1770
dc.contributor.authorDeğirmenci, Aysun
dc.contributor.authorAlgı, Fatih
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T09:14:54Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T09:14:54Z
dc.date.issued2017
dc.departmentSabire Yazıcı Fen Edebiyat Fakültesi
dc.description.abstractThe design, synthesis and energy transfer efficiency of a new covalently linked molecular dyad 5, which consists of 2,3-dihydrophthalazine-1,4-dione and BODIPY scaffolds, are reported. It is noteworthy that dyad 5 can induce chemiluminescence upon treatment with alkaline H2O2 in the presence of Fe(III) ions. This reaction triggers chemiluminescence resonance energy transfer (CRET) from 2,3-dihydrophthalazine-1,4-dione unit to BODIPY fluorophore, which act as the donor and the acceptor components, respectively. To our best knowledge, this is the first example of a covalently linked molecular dyad consisting of chemiluminogenic 2,3-dihydrophthalazine-1,4-dione and BODIPY dye. Importantly, dyad 5 can provide a low energy emitting material via the chemiluminescence energy transfer (CRET), which covers almost the entire visible region (400 nm-700 nm) of the electromagnetic spectrum. (C) 2017 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipTurkish Academy of Sciences (TUBA) Young Investigator Award Programme (GEBIP); Aksaray University; Scientific and Technological Research Council of Turkey (TUBITAK)
dc.description.sponsorshipWe are grateful to Turkish Academy of Sciences (TUBA) Young Investigator Award Programme (GEBIP) and Aksaray University for partial financial support of our projects. A. D. is indebted to Scientific and Technological Research Council of Turkey (TUBITAK) for a graduate fellowship.
dc.identifier.doi10.1016/j.dyepig.2017.01.037
dc.identifier.endpage99en_US
dc.identifier.issn0143-7208
dc.identifier.issn1873-3743
dc.identifier.scopusqualityQ1
dc.identifier.startpage92en_US
dc.identifier.urihttps://doi.org/10.1016/j.dyepig.2017.01.037
dc.identifier.urihttps://hdl.handle.net/20.500.12451/4203
dc.identifier.volume140en_US
dc.identifier.wosWOS:000395212100013
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Ltd.
dc.relation.ispartofDyes and Pigments
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectChemiluminescence
dc.subject2,3-Dihydrophthalazine-1,4-Dione
dc.subjectBODIPY
dc.subjectCRET
dc.subjectPyridazine
dc.titleSynthesis, chemiluminescence and energy transfer efficiency of 2,3-dihydrophthalazine-1,4-dione and BODIPY dyad
dc.typeArticle

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