Seasonal dynamics and pre-treatment influences on NOM fractions and THM formation potential in a drinking water reservoir: A case study in Aksaray, Turkey

dc.authorid0000-0003-2734-8544
dc.authorid0000-0002-1628-5026
dc.authorid0000-0002-2365-3093
dc.contributor.authorAlver, Alper
dc.contributor.authorBaştürk, Emine
dc.contributor.authorKılıç, Ahmet
dc.date.accessioned2025-07-10T07:49:02Z
dc.date.available2025-07-10T07:49:02Z
dc.date.issued2025
dc.departmentMühendislik Fakültesi
dc.description.abstractIn this study, the seasonal variations of natural organic matter (NOM) and the effects of pre-chlorination and pre-ozonation on disinfection by-product (DBP) formation in Mamasın Dam were investigated. NOM was classified into hydrophilic acids (HIA), hydrophobic neutrals (HON), and other fractions to assess their contributions to trihalomethanes (THMs). Seasonal differences were significant, with total organic carbon (TOC) peaking at 6.564 mg/L in summer due to increased biological activity and dropping to 3.173 mg/L in winter. Pretreatment influenced NOM distribution, with pre-ozonation effectively reducing reactive HON and HIN fractions, leading to a decrease in THM formation potential (THMFP) from 292.5 μg/L in raw summer water to 247.9 μg/L. Regression models (R2 > 0.999) confirmed that HIA and HIN were the dominant THM precursors across all THM species. Model performance was further validated using 10-fold cross-validation, yielding high predictive accuracy across all THM species and confirming the absence of overfitting. Pre-ozonation was more effective than pre-chlorination in lowering THMFP, particularly chloroform, highlighting its superior potential for DBP control. These findings emphasize the critical role of seasonal changes and treatment strategies in NOM reactivity and DBP mitigation. This study provides a framework for fraction-specific and adaptive treatment approaches to improve drinking water safety.
dc.identifier.doi10.1016/j.jwpe.2025.107977
dc.identifier.issn22147144
dc.identifier.scopus105005503904
dc.identifier.urihttps://dx.doi.org/10.1016/j.jwpe.2025.107977
dc.identifier.urihttps://hdl.handle.net/20.500.12451/13231
dc.identifier.volume75
dc.identifier.wosWOS:001502004800006
dc.identifier.wosqualityQ2
dc.indekslendigikaynakScopus
dc.indekslendigikaynakWeb of Science
dc.institutionauthorAlver, Alper
dc.institutionauthorBaştürk, Emine
dc.institutionauthorKılıç, Ahmet
dc.institutionauthorid0000-0003-2734-8544
dc.institutionauthorid0000-0002-1628-5026
dc.institutionauthorid0000-0002-2365-3093
dc.language.isoen
dc.publisherElsevier Ltd
dc.relation.ispartofJournal of Water Process Engineering
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectDisinfection by-products
dc.subjectFraction
dc.subjectModel
dc.subjectNatural organic matter
dc.subjectPre-treatment
dc.subjectTrihalomethanes
dc.titleSeasonal dynamics and pre-treatment influences on NOM fractions and THM formation potential in a drinking water reservoir: A case study in Aksaray, Turkey
dc.typeArticle

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