A new air and moisture stable robust bio-polymer based palladium catalyst for highly efficient synthesis of biaryl compounds

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dc.contributor.authorBaran, Talat
dc.contributor.authorYılmaz Baran, Nuray
dc.contributor.authorMenteş, Ayfer
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-29T19:27:56Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-29T19:27:56Z
dc.date.issued2018
dc.departmentSabire Yazıcı Fen Edebiyat Fakültesi
dc.description.abstractThe designs of robust natural polymer based catalysts are important for catalytic systems in the view of industrial purposes and green chemistry. In this study, a new air and moisture stable robust starch-based Pd(II) catalyst was designed and characterized with different analytical techniques. Catalytic behavior of the prepared robust palladium(II) catalyst was investigated in the Suzuki coupling reactions of aryl iodides, aryl bromides and aryl chlorides with phenyl boronic acid under microwave irradiation using very short reaction time. Sustainability and reusability of the catalyst was also explored under benign conditions. As a result of the catalytic tests, the green catalyst gave excellent biphenyl yields, TONs and TOFs with very low catalyst loading. More importantly, the robust catalyst has showed that it can be reused several times without important loses from its activity in the coupling reactions. The study showed that the robust starch-based Pd(II) catalyst had more advantages than other catalysts reported in the literature due to its economic, sustainable, thermal durable, environmentally friendly and practice properties.
dc.identifier.doi10.1002/aoc.4076
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1002/aoc.4076
dc.identifier.urihttps://hdl.handle.net/20.500.12451/5957
dc.identifier.volume32en_US
dc.identifier.wosWOS:000423670000081
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectBiphenyl
dc.subjectNinhydrin Test
dc.subjectRobust Catalyst
dc.subjectStarch
dc.subjectTOF
dc.titleA new air and moisture stable robust bio-polymer based palladium catalyst for highly efficient synthesis of biaryl compounds
dc.typeArticle

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