Crystal structure of trans-diaquabis(4-cyanobenzoato-?O)bis(nicotinamide-?N 1)cobalt(II)

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dc.authoridHokelek, Tuncer -- 0000-0002-8602-4382;
dc.contributor.authorAşkın, Gülçin Şefiye
dc.contributor.authorNecefoğlu, Hacali
dc.contributor.authorNayır, Gamze Yılmaz
dc.contributor.authorÇelik, Raziye Çatak
dc.contributor.authorHökelek, Tuncer
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T09:15:42Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T09:15:42Z
dc.date.issued2015
dc.departmentBilimsel ve Teknolojik Uygulama ve Araştırma Merkezi
dc.description.abstractIn the title complex, [Co(C8H4NO2)(2)(C6H6N2O)(2)(H2O)(2)], the Co-II atom is located on an inversion centre and is coordinated by two 4-cyanobenzoate (CNB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination sphere is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 22.11 (15)degrees, while the pyridine and benzene rings are oriented at a dihedral angle of 89.98 (5)degrees. In the crystal, intermolecular N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the molecules, enclosing R-2(2)(8) and R-4(4)(8) ring motifs, forming layers parallel to (100). The layers are linked via C-H center dot center dot center dot O and C-H center dot center dot center dot N hydrogen bonds, resulting in a three-dimensional network. A weak C-H center dot center dot center dot pi interaction is also observed.
dc.description.sponsorshipAksaray University, Science and Technology Application and Research Center, Aksaray, Turkey [2010K120480]
dc.description.sponsorshipThe authors acknowledge the Aksaray University, Science and Technology Application and Research Center, Aksaray, Turkey, for the use of the Bruker SMART BREEZE CCD diffractometer (purchased under grant No. 2010K120480 of the State Planning Organization).
dc.identifier.doi10.1107/S2056989015008270
dc.identifier.endpage+en_US
dc.identifier.issn2056-9890
dc.identifier.pmid25995880
dc.identifier.scopusqualityQ3
dc.identifier.startpage561en_US
dc.identifier.urihttps://doi.org/10.1107/S2056989015008270
dc.identifier.urihttps://hdl.handle.net/20.500.12451/4447
dc.identifier.volume71en_US
dc.identifier.wosWOS:000369977900105
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherInternational Union of Crystallography
dc.relation.ispartofActa Crystallographica Section e-Crystallographic Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectCrystal Structure
dc.subjectCobalt(II)
dc.subjectTransition Metal Complexes of Benzoic Acid and Nicotinamide Derivatives
dc.titleCrystal structure of trans-diaquabis(4-cyanobenzoato-?O)bis(nicotinamide-?N 1)cobalt(II)
dc.typeArticle

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