?,??-diamino- p-tetrafluoroquinodimethane: stability of one- and two-electron oxidized species and fixation of molecular oxygen
| dc.contributor.author | Mahata, Alok | |
| dc.contributor.author | Chrysochos, Nikolas | |
| dc.contributor.author | Krummenacher, Ivo | |
| dc.contributor.author | Chandra, S. | |
| dc.contributor.author | Braunschweig, H. | |
| dc.contributor.author | Schulzke, C. | |
| dc.contributor.author | Sarkar, B. | |
| dc.contributor.author | Yıldız, Cem Burak | |
| dc.contributor.author | Jana, A. | |
| dc.date.accessioned | 2021-11-09T06:15:35Z | |
| dc.date.available | 2021-11-09T06:15:35Z | |
| dc.date.issued | 2021 | |
| dc.department | Teknik Bilimler Meslek Yüksekokulu | |
| dc.description.abstract | Herein, we report the synthesis, characterization, and reactivity of ?,??-diamino-p-tetrafluoroquinodimethane, a p-tetrafluorophenylene-bridged monosubstituted carbene-based Thiele's hydrocarbon A. The compound exhibits a reversible two-step one-electron oxidation with a marginally stable radical cation state B. The in situ formation of the radical cation could be confirmed by electron paramagnetic resonance spectroscopy. | |
| dc.identifier.doi | 10.1021/acs.joc.1c01120 | |
| dc.identifier.endpage | 10473 | en_US |
| dc.identifier.issn | 0022-3263 | |
| dc.identifier.issue | 15 | en_US |
| dc.identifier.pmid | 34269573 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 10467 | en_US |
| dc.identifier.uri | https:/dx.doi.org/10.1021/acs.joc.1c01120 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12451/8610 | |
| dc.identifier.volume | 86 | en_US |
| dc.identifier.wos | WOS:000684025500043 | |
| dc.identifier.wosquality | Q1 | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.relation.ispartof | Journal of Organic Chemistry | |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
| dc.rights | info:eu-repo/semantics/embargoedAccess | |
| dc.subject | ?,??-Diamino- p-tetrafluoroquinodimethane | |
| dc.title | ?,??-diamino- p-tetrafluoroquinodimethane: stability of one- and two-electron oxidized species and fixation of molecular oxygen | |
| dc.type | Article |
