?,??-diamino- p-tetrafluoroquinodimethane: stability of one- and two-electron oxidized species and fixation of molecular oxygen
Yükleniyor...
Dosyalar
Tarih
2021
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
American Chemical Society
Erişim Hakkı
info:eu-repo/semantics/embargoedAccess
Özet
Herein, we report the synthesis, characterization, and reactivity of ?,??-diamino-p-tetrafluoroquinodimethane, a p-tetrafluorophenylene-bridged monosubstituted carbene-based Thiele's hydrocarbon A. The compound exhibits a reversible two-step one-electron oxidation with a marginally stable radical cation state B. The in situ formation of the radical cation could be confirmed by electron paramagnetic resonance spectroscopy.
Açıklama
Anahtar Kelimeler
?,??-Diamino- p-tetrafluoroquinodimethane
Kaynak
Journal of Organic Chemistry
WoS Q Değeri
Q1
Scopus Q Değeri
Q2
Cilt
86
Sayı
15
