Coordination Chemistry of the Antimony(III) and Bismuth(III) Cations using Bis(?-iminopyridine) as Ligand
| dc.contributor.author | Haldar, Hritwik | |
| dc.contributor.author | Yıldız, Cem Burak | |
| dc.contributor.author | Majumdar, Moumita | |
| dc.date.accessioned | 2023-10-02T06:50:40Z | |
| dc.date.available | 2023-10-02T06:50:40Z | |
| dc.date.issued | 2023 | |
| dc.department | Teknik Bilimler Meslek Yüksekokulu | |
| dc.description.abstract | Bis(alpha-iminopyridine) L has been employed as the redox non-innocent Schiff-base ligand to coordinate with cationic antimony(III) and bismuth(III) centers. Mono- and di- cationic compounds: [LSbCl2][CF3SO3] 1, [LBiCl2][CF3SO3] 2, [LSbCl2]2[Sb2Cl8] 3, [LBiCl2]2[Bi2Cl8] 4, [LSbCl][CF3SO3]2 5, [LBiCl][CF3SO3]2 6 have been isolated and characterized using single crystal X-ray crystallography in the solid-state and solution-state NMR studies. These compounds have been prepared from PnCl3 (Pn=Sb, Bi) and chloride abstracting agent such as Me3SiCF3SO3 or AgCF3SO3 in the presence of L. The Bi tri-cationic species forms heteroleptic compound 7, being coordinated by two types of Schiff-base donors L and L?. The latter has been in situ generated by the cleavage of one of the two imines present in L. | |
| dc.identifier.doi | 10.1002/cplu.202300211 | |
| dc.identifier.issn | 2192-6506 | |
| dc.identifier.issue | 7 | en_US |
| dc.identifier.pmid | 37394682 | |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.uri | https:/dx.doi.org10.1002/cplu.202300211 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12451/11026 | |
| dc.identifier.volume | 88 | en_US |
| dc.identifier.wos | WOS:001029655300001 | |
| dc.identifier.wosquality | Q2 | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.indekslendigikaynak | PubMed | |
| dc.language.iso | en | |
| dc.publisher | John Wiley and Sons Inc | |
| dc.relation.ispartof | ChemPlusChem | |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
| dc.rights | info:eu-repo/semantics/embargoedAccess | |
| dc.subject | Antimony(III | |
| dc.subject | Bismuth(III) | |
| dc.subject | Cation | |
| dc.subject | Coordination | |
| dc.subject | Schiff Base | |
| dc.title | Coordination Chemistry of the Antimony(III) and Bismuth(III) Cations using Bis(?-iminopyridine) as Ligand | |
| dc.type | Article |
