Electrocatalytic hydrogen production on GCE/RGO/Au hybrid electrode

dc.contributor.authorBalun Kayan, Didem
dc.contributor.authorKoçak, Derya
dc.contributor.authorİlhan, Merve
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T08:25:53Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T08:25:53Z
dc.date.issued2018
dc.departmentSabire Yazıcı Fen Edebiyat Fakültesi
dc.description.abstractWe have prepared a nanocomposite hybrid film to produce a collaborative network of gold (Au) nanoparticles that are highly dispersed on reduced graphene oxide (RGO) sheets, and tested it for electrocatalytic hydrogen production. The RGO/Au nanocomposite film synthesized on glassy carbon electrode (GCE) allows significant improvements to the electron-transfer process. The Au nanoparticles decorated on the surface of graphene increases the electron density, which synergistically promote the adsorption of hydrogen atoms on the graphene sheets and consequently enhance the hydrogen evolution reaction (HER) activity. The surface properties of the composite was characterized by field-emission scanning electron microscopy (FE-SEM) and the electrocatalytical performances evaluated as-prepared electrocatalyst toward (HER) by linear sweep voltammetry (LSV), Tafel polarization curves and electrochemical impedance spectroscopy (EIS) analyses. The GCE/RGO/Au nanohybrid electrode exhibited good catalytic activity for HER with an onset potential of -0.3 V and a Tafel slope of 136 mV dec-1, achieving a current density of 10 mA cm-2 at an overpotential of -0.43 V. © 2018 Hydrogen Energy Publications LLC
dc.description.sponsorshipFirat University Scientific Research Projects Management Unit
dc.description.sponsorshipThe authors thank the Aksaray University Scientific Research Projects Coordination Unit (ASU-BAP, 2016-034 ) for financial support.
dc.identifier.doi10.1016/j.ijhydene.2018.01.077
dc.identifier.endpage10568en_US
dc.identifier.issn0360-3199
dc.identifier.issue23en_US
dc.identifier.scopusqualityQ1
dc.identifier.startpage10562en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.ijhydene.2018.01.077
dc.identifier.urihttps://hdl.handle.net/20.500.12451/3100
dc.identifier.volume43en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Ltd
dc.relation.ispartofInternational Journal of Hydrogen Energy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectAu Nanoparticles
dc.subjectHydrogen Evolution Reaction
dc.subjectNanocomposite
dc.subjectReduced Graphene Oxide
dc.titleElectrocatalytic hydrogen production on GCE/RGO/Au hybrid electrode
dc.typeArticle

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