Sustainable chitosan/starch composite material for stabilization of palladium nanoparticles: Synthesis, characterization and investigation of catalytic behaviour of Pd@chitosan/starch nanocomposite in Suzuki–Miyaura reaction

dc.contributor.authorBaran, Talat
dc.contributor.authorBaran, Nuray Yılmaz
dc.contributor.authorMenteş, Ayfer
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-29T19:26:56Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-29T19:26:56Z
dc.date.issued2018
dc.departmentFen-Edebiyat Fakültesi
dc.description.abstractWe fabricated a green chitosan/starch composite as support material for stabilization of palladium nanoparticles for the first time. The chemical structure of the sustainable palladium nanocomposite was investigated using various techniques. Characterization studies showed that the average dimensions of the palladium nanocomposite ranged between 16 and 21nm. The synthesized palladium nanocomposite was employed in the synthesis of a series of biphenyl compounds via Suzuki-Miyaura cross-coupling reactions with an unconventional technique. All coupling reactions were conducted in very short reaction time and excellent biphenyl yields were obtained in the presence of the nanocomposite. The palladium catalyst was tolerant to a wide range of functional groups. We also investigated the recyclability and reusability of the palladium nanocomposite, and found that it could be used for seven successive cycles.
dc.identifier.doi10.1002/aoc.4075
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue2en_US
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1002/aoc.4075
dc.identifier.urihttps://hdl.handle.net/20.500.12451/5748
dc.identifier.volume32en_US
dc.identifier.wosWOS:000423670000080
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherWiley
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectChitosan
dc.subjectNanocomposite
dc.subjectReusability
dc.subjectStarch
dc.titleSustainable chitosan/starch composite material for stabilization of palladium nanoparticles: Synthesis, characterization and investigation of catalytic behaviour of Pd@chitosan/starch nanocomposite in Suzuki–Miyaura reaction
dc.typeArticle

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