Crystal structure of 4,4'-bipyridine-1,1'-diium naphthalene-2,6-disulfonate dihydrate

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dc.contributor.authorÇevik, Sabri
dc.contributor.authorSarı, Musa
dc.contributor.authorSarı, Murat
dc.contributor.authorTunç, Tuncay
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T08:22:39Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T08:22:39Z
dc.date.issued2014
dc.departmentEğitim Fakültesi
dc.description.abstractThe title hydrated molecular organic salt, C10H10N22+C10H6O6S22-2H2O, crystallized with half a bipyridinium cation, half a naphthalene-2,6-disulfonate anion and a water molecule in the asymmetric unit. The whole cation and anion are generated by inversion symmetry, the inversion centers being at the center of the bridging C - C bond of the cation, and at the center of the fused C - C bond of the naphthalene group of the anion. In the crystal, the anions and cations stack alternately along the a axis with ?-? interactions [inter-centroid distance = 3.491 (1) Å]. The anions are linked via O - O(sulfonate) hydrogen bonds involving two inversion-related water molecules, forming chains along [10-1]. These chains are bridged by bifurcated N - (O,O) hydrogen bonds, forming a three-dimensional framework structure. There are also C - O hydrogen bonds present, reinforcing the framework structure.
dc.identifier.doi10.1107/S160053681401784X
dc.identifier.endpageo900en_US
dc.identifier.issn1600-5368
dc.identifier.issue9en_US
dc.identifier.scopusqualityN/A
dc.identifier.startpageo989en_US
dc.identifier.urihttps://dx.doi.org/10.1107/S160053681401784X
dc.identifier.urihttps://hdl.handle.net/20.500.12451/2612
dc.identifier.volume70en_US
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherInternational Union of Crystallography
dc.relation.ispartofActa Crystallographica Section E: Structure Reports Online
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectBipyridine
dc.subjectCrystal Structure
dc.subjectDihydrate
dc.subjectMolecular Salt
dc.subjectNathphalenedisulfonate
dc.titleCrystal structure of 4,4'-bipyridine-1,1'-diium naphthalene-2,6-disulfonate dihydrate
dc.typeArticle

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