UV- and US-Based Oxidation of a Triazine Azo Dye (Reactive Red 120): Operational Parameters, Kinetics, Water Matrix Effect, Predominant Radicals, and Energy Efficiency

dc.contributor.authorBaştürk, Emine
dc.date.accessioned2024-04-18T11:16:35Z
dc.date.available2024-04-18T11:16:35Z
dc.date.issued2024
dc.departmentMühendislik Fakültesi
dc.description.abstractIn this work, ultraviolet (UV)-/ultrasound (US)-based advanced oxidation processes were used to removal of Reactive Red 120 (RR120). The optimum conditions were determined as initial dye concentration = 100mg L?1, hydrogen peroxide concentration (H2O2) = 100 mg L?1, pH = 3 for the UV/H2O2 process, iron dosage (Fe2+) = 50 mg L?1, [H2O2] = 250mg L?1, pH = 3, ultrasound frequency = 53 kHz, and ultrasound power = 90 W for the sono-Fenton (Fe/H2O2/US) process. Besides, in the mineralization study, total organic carbon (TOC) reductions were 37.5%, 43.7%, 50.5%, and 58.9% for Fe/H2O2/US, UV/H2O2, foto-Fenton (Fe/H2O2/UV), and sono-photo-Fenton (Fe/H2O2/UV/US) processes, respectively. The sole and other processes removal percentages were below 27%. These results help us to understand how these different advanced oxidation processes removal performances by means of decolorization efficiencies are similar like as TOC reduction. A significant reduction in removal performance (27.8% because tert-butyl alcohol) of was found compared with no addition of radical scavenger (89.2%) in UV/H2O2. For sono-Fenton, the same situation was occurred, and the removal efficiency was decreased from 70.2 to 42.5% because of sodium azide radical scavenger. In the water matrix study, regardless of this process in the area of removal performance, the major issue of some ions persistence. (The performance declined 89.2–40.7% due to the carbonate ions for UV/H2O2; increased 70.2–82.1% due to the carbonate ions for sono-Fenton.) These findings may shed light on these processes’ behavior of azo dyes in some specific scenarios such as laboratory or pilot scale utilization.
dc.identifier.doi10.1007/s13369-023-08479-0
dc.identifier.issn2193-567X
dc.identifier.scopusqualityQ1
dc.identifier.urihttps:/dx.doi.org10.1007/s13369-023-08479-0
dc.identifier.urihttps://hdl.handle.net/20.500.12451/11642
dc.identifier.wosWOS:001113785200007
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherInstitute for Ionics
dc.relation.ispartofArabian Journal for Science and Engineering
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectDetrimental Compounds
dc.subjectEnergy Efficiency
dc.subjectKinetic
dc.subjectPredominant Radicals
dc.subjectWater Matrix Effect
dc.titleUV- and US-Based Oxidation of a Triazine Azo Dye (Reactive Red 120): Operational Parameters, Kinetics, Water Matrix Effect, Predominant Radicals, and Energy Efficiency
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
basturk-emine-2023.pdf
Boyut:
1.6 MB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin / Full Text
Lisans paketi
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
license.txt
Boyut:
1.44 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama: