A highly selective dual channel hypochlorite probe based on fluorescein and 1,10-phenanthroline
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Tarih
2016
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
In this study, a highly selective dual channel (UV-vis and fluorescence) responsive hypochlorite probe based on fluorescein and 1,10-phenanthroline is described. It is found that this compound can be used as both a fluorogenic and chromogenic probe for the detection of the hypochlorite ion in aqueous solution. NMR and mass spectral analysis show that the probe reacts with the hypochlorite ion, which triggers both a remarkable enhancement of the emission intensity (turn on), and a color change from a colorless state to yellow. More importantly, the probe displays extremely high selectivity to hypochlorite among other common ROS and many ions in aqueous solution. (C) 2016 Elsevier Ltd. All rights reserved.
Açıklama
Anahtar Kelimeler
Fluorescence, Probe, Hypochlorite, 1,10-Phenanthroline, Fluorescein, Chromogenic
Kaynak
Tetrahedron
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
72
Sayı
12
