Studies on synthesis, structure, and DNA cleaving of homo-dinuclear Mn(II), Cu(II), Ni(II), and Zn(II) complexes with a heterocycle-based macroacyclic Schiff base

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dc.authoridKARAOGLU, Kaan -- 0000-0003-3265-8328; BARAN, TALAT -- 0000-0003-0206-3841; SANDALLI, Cemal -- 0000-0002-1298-3687
dc.contributor.authorBaran, Talat
dc.contributor.authorKaraoğlu, Kaan
dc.contributor.authorSerbest, Kerim
dc.contributor.authorA?ır, Hülya
dc.contributor.authorSandalli, Cemal
dc.contributor.authorDe?irmencio?lu, İsmail
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T09:15:01Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T09:15:01Z
dc.date.issued2013
dc.departmentFen-Edebiyat Fakültesi
dc.description.abstract(E,E',E'',E''')-N,N',N'',N'''-[(1,2-ethenyliden)tetrakis[methylenoxy(2,1-naphthalinediyl)methylidyne]tetrakis[1,2,4-triazol-4-amine] and its novel homo-dinuclear Mn(II), Ni(II), Cu(II), and Zn(II) complexes have been synthesized and characterized by elemental analyses, spectroscopic data (i.e., IR, H-1 and C-13 NMR, UV-Vis), electrospray ionisation mass spectra, XRD, DSC, molar conductivity, and magnetic susceptibility measurements. The absorption bands observed in the electronic spectra and magnetic moment values confirm an octahedral environment around the metal ion. The molar conductivity measurements confirm the non-ionic character of these complexes. The DNA cleavage activities of the Schiff base and its homo-dinuclear complexes are also investigated. Results suggest that all the complexes used can be evaluated as nuclease mimics.
dc.description.sponsorshipScientific and Technological Research Council of TURKEY (TUBITAK) [107T383]
dc.description.sponsorshipThe authors thank the Scientific and Technological Research Council of TURKEY (TUBITAK) for financial support (Project Number: 107T383).
dc.identifier.doi10.1007/s00706-013-0926-6
dc.identifier.endpage1115en_US
dc.identifier.issn0026-9247
dc.identifier.issn1434-4475
dc.identifier.issue8en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage1107en_US
dc.identifier.urihttps://doi.org/10.1007/s00706-013-0926-6
dc.identifier.urihttps://hdl.handle.net/20.500.12451/4257
dc.identifier.volume144en_US
dc.identifier.wosWOS:000321920800003
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSPRINGER WIEN
dc.relation.ispartofMONATSHEFTE FUR CHEMIE
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectCoordination Chemistry
dc.subjectHeterocycles
dc.subjectSchiff Bases
dc.subjectBinucleating
dc.subjectDNA Cleaving
dc.titleStudies on synthesis, structure, and DNA cleaving of homo-dinuclear Mn(II), Cu(II), Ni(II), and Zn(II) complexes with a heterocycle-based macroacyclic Schiff base
dc.typeArticle

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