Synthesis, crystal structure and spectroscopic studies of 2-{(E)-[2-hydroxyphenyl)imino]methyl} phenol schiff base molecule

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dc.authoridFen Bilgisi Egitimi, Aksaray Egitim -- 0000-0001-8976-571X; Tunc, Tuncay -- 0000-0002-3576-2633;
dc.contributor.authorTunç, Tuncay
dc.contributor.authorSarı, Musa
dc.contributor.authorSadıkoğlu, Murat
dc.contributor.authorBüyükgüngör, Orhan
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-29T19:27:31Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-29T19:27:31Z
dc.date.issued2009
dc.departmentEğitim Fakültesi
dc.description.abstractA new Schiff-base complex 2-{(E)-[2-hydroxyphenyl)imino]methyl}phenol has been synthesized and characterized by elemental analyses, UV-VIS and IR spectroscopy and single crystal X-ray determination. The structure comprises two independent and similar molecules. The two independent molecules in the asymmetric unit are hydrogen bonded and have different conformations. In each molecule, C13H11NO2, adopt an E configuration about the azomethine C-N double bond. The complex crystallized in the triclinic space group P-1. Two benzene rings and azomethine group are practically coplanar, as a result of intramolecular hydrogen bonds involving the hydroxy O atom and azomethine N atom. Also hydroxy group of the molecule is the presence intermolecular O-H center dot center dot center dot O hydrogen bonds with the hydroxy group of the other molecule.
dc.description.sponsorshipUniversity Research Fund [F. 279]
dc.description.sponsorshipThe authors thank to acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for use of the Stoe IPDS-2 diffractometer purchased under grant F. 279 of the University Research Fund.
dc.identifier.doi10.1007/s10870-009-9556-6
dc.identifier.endpage676en_US
dc.identifier.issn1074-1542
dc.identifier.issn1572-8854
dc.identifier.issue9en_US
dc.identifier.scopusqualityQ3
dc.identifier.startpage672en_US
dc.identifier.urihttps://doi.org/10.1007/s10870-009-9556-6
dc.identifier.urihttps://hdl.handle.net/20.500.12451/5879
dc.identifier.volume39en_US
dc.identifier.wosWOS:000268300800012
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer/Plenum Publishers
dc.relation.ispartofJournal of Chemical Crystallography
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectCrystal Structure
dc.subjectSchiff Base
dc.subjectHydroxypheny
dc.subjectPhenol
dc.titleSynthesis, crystal structure and spectroscopic studies of 2-{(E)-[2-hydroxyphenyl)imino]methyl} phenol schiff base molecule
dc.typeArticle

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