?,??-Diamino-p-quinodimethanes with three stable oxidation states
dc.authorid | 0000-0002-0424-4673 | |
dc.authorid | 0000-0003-4887-7277 | |
dc.contributor.author | Mahata, Alok | |
dc.contributor.author | Chandra, Shubhadeep | |
dc.contributor.author | Maiti, Avijit | |
dc.contributor.author | Rao, D. Krishna | |
dc.contributor.author | Yıldız, Cem Burak | |
dc.contributor.author | Sarkar, Biprajit | |
dc.contributor.author | Jana, Anukul | |
dc.date.accessioned | 2021-06-16T06:55:40Z | |
dc.date.available | 2021-06-16T06:55:40Z | |
dc.date.issued | 2020 | |
dc.department | Teknik Bilimler Meslek Yüksekokulu | |
dc.description | *Yıldız, Cem Burak ( Aksaray, Yazar ) | |
dc.description.abstract | Herein, we report the rational design, synthesis, and characterization of ?,??-diamino-substituted-p-quinodimethanes, which are a group of partially substituted p-quinodimethanes. These exhibit two reversible one-electron redox steps and electrochromism in the ultraviolet, visible, and near-infrared regions. We were able to isolate the crystalline compounds of all three oxidation states: neutral, radical cation, and dication. The obtained results not only create the bridge between p-quinodimethane and ?,?,??,??-tetrasubstituted-p-quinodimethane, but also demonstrate the straightforward modular approach for the synthesis of ?-conjugated open-shell compounds. | |
dc.identifier.doi | 10.1021/acs.orglett.0c02964 | |
dc.identifier.endpage | 8336 | en_US |
dc.identifier.issn | 1523-7060 | |
dc.identifier.issue | 21 | en_US |
dc.identifier.pmid | 33058728 | |
dc.identifier.scopusquality | Q1 | |
dc.identifier.startpage | 8332 | en_US |
dc.identifier.uri | https:/dx.doi.org/10.1021/acs.orglett.0c02964 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12451/8109 | |
dc.identifier.volume | 22 | en_US |
dc.identifier.wos | WOS:000589942900029 | |
dc.identifier.wosquality | Q1 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | Scopus | |
dc.indekslendigikaynak | PubMed | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | |
dc.relation.ispartof | Organic Letters | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
dc.rights | info:eu-repo/semantics/embargoedAccess | |
dc.subject | ?,??-Diamino?p?quinodimethanes | |
dc.subject | Three Stable Oxidation States | |
dc.title | ?,??-Diamino-p-quinodimethanes with three stable oxidation states | |
dc.type | Article |