?,??-Diamino-p-quinodimethanes with three stable oxidation states

dc.authorid0000-0002-0424-4673
dc.authorid0000-0003-4887-7277
dc.contributor.authorMahata, Alok
dc.contributor.authorChandra, Shubhadeep
dc.contributor.authorMaiti, Avijit
dc.contributor.authorRao, D. Krishna
dc.contributor.authorYıldız, Cem Burak
dc.contributor.authorSarkar, Biprajit
dc.contributor.authorJana, Anukul
dc.date.accessioned2021-06-16T06:55:40Z
dc.date.available2021-06-16T06:55:40Z
dc.date.issued2020
dc.departmentTeknik Bilimler Meslek Yüksekokulu
dc.description*Yıldız, Cem Burak ( Aksaray, Yazar )
dc.description.abstractHerein, we report the rational design, synthesis, and characterization of ?,??-diamino-substituted-p-quinodimethanes, which are a group of partially substituted p-quinodimethanes. These exhibit two reversible one-electron redox steps and electrochromism in the ultraviolet, visible, and near-infrared regions. We were able to isolate the crystalline compounds of all three oxidation states: neutral, radical cation, and dication. The obtained results not only create the bridge between p-quinodimethane and ?,?,??,??-tetrasubstituted-p-quinodimethane, but also demonstrate the straightforward modular approach for the synthesis of ?-conjugated open-shell compounds.
dc.identifier.doi10.1021/acs.orglett.0c02964
dc.identifier.endpage8336en_US
dc.identifier.issn1523-7060
dc.identifier.issue21en_US
dc.identifier.pmid33058728
dc.identifier.scopusqualityQ1
dc.identifier.startpage8332en_US
dc.identifier.urihttps:/dx.doi.org/10.1021/acs.orglett.0c02964
dc.identifier.urihttps://hdl.handle.net/20.500.12451/8109
dc.identifier.volume22en_US
dc.identifier.wosWOS:000589942900029
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.relation.ispartofOrganic Letters
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subject?,??-Diamino?p?quinodimethanes
dc.subjectThree Stable Oxidation States
dc.title?,??-Diamino-p-quinodimethanes with three stable oxidation states
dc.typeArticle

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