Equilibrium Formation of Stable All-Silicon Versions of 1,3-Cyclobutanediyl
| dc.authorid | 0000-0002-0424-4673 | |
| dc.authorid | 0000-0002-5098-1842 | |
| dc.authorid | 0000-0002-8635-8390 | |
| dc.contributor.author | Yıldız, Cem Burak | |
| dc.contributor.author | Leszczyñska, Kinga I. | |
| dc.contributor.author | González-Gallardo, Sandra | |
| dc.contributor.author | Zimmer, Michael | |
| dc.contributor.author | Azizoğlu, Akın | |
| dc.contributor.author | Biskup, Till | |
| dc.contributor.author | Kay, Christopher | |
| dc.contributor.author | Hüch, Volker | |
| dc.contributor.author | Rzepa, Henry S. | |
| dc.contributor.author | Scheschkewitz, David | |
| dc.date.accessioned | 2020-09-09T06:40:57Z | |
| dc.date.available | 2020-09-09T06:40:57Z | |
| dc.date.issued | 2020 | |
| dc.department | Teknik Bilimler Meslek Yüksekokulu | |
| dc.description | Yıldız, Cem Burak ( Aksaray, Yazar ) | |
| dc.description.abstract | Main group analogues of cyclobutane-1,3-diyls are fascinating due to their unique reactivity and electronic properties. So far only heteronuclear examples have been isolated. Here we report the isolation and characterization of all-silicon 1,3-cyclobutanediyls as stable closed-shell singlet species from the reversible reactions of cyclotrisilene c-Si3Tip4 (Tip=2,4,6-triisopropylphenyl) with the N-heterocyclic silylenes c-[(CR2CH2)(NtBu)2]Si: (R=H or methyl) with saturated backbones. At elevated temperatures, tetrasilacyclobutenes are obtained from these equilibrium mixtures. The corresponding reaction with the unsaturated N-heterocyclic silylene c-(CH)2(NtBu)2Si: proceeds directly to the corresponding tetrasilacyclobutene without detection of the assumed 1,3-cyclobutanediyl intermediate. | |
| dc.identifier.doi | 10.1002/anie.202006283 | |
| dc.identifier.endpage | 15092 | en_US |
| dc.identifier.issn | 1433-7851 | |
| dc.identifier.issue | 35 | en_US |
| dc.identifier.pmid | 32407571 | |
| dc.identifier.scopusquality | Q1 | |
| dc.identifier.startpage | 15087 | en_US |
| dc.identifier.uri | https:/dx.doi.org/10.1002/anie.202006283 | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12451/7668 | |
| dc.identifier.volume | 59 | en_US |
| dc.identifier.wos | WOS:000559916900046 | |
| dc.identifier.wosquality | Q1 | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.indekslendigikaynak | PubMed | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.relation.ispartof | Angewandte Chemie - International Edition | |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.subject | Diradicaloids | |
| dc.subject | Low-valent Species | |
| dc.subject | Silicon | |
| dc.subject | Small Ring | |
| dc.subject | Synthesis | |
| dc.title | Equilibrium Formation of Stable All-Silicon Versions of 1,3-Cyclobutanediyl | |
| dc.type | Article |
