Separation of dimethylformamide/water mixtures through sodium alginate and sodium alginate/clinoptilolite composite membranes by vapor permeation with and without feed-membrane temperature difference

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Date

2014

Journal Title

Journal ISSN

Volume Title

Publisher

TAYLOR & FRANCIS INC

Access Rights

info:eu-repo/semantics/closedAccess

Abstract

The characteristics of permeation and separation of dimethylformamide (DMF)/water mixtures through crosslinked sodium alginate (NaAlg) and NaAlg/clinoptilolite (Clt) composite membranes were investigated by vapor permeation (VP) and vapor permeation with temperature-difference (TDVP) techniques. The effects of Clt content of the membrane, feed composition, permeation temperature, and membrane surrounding temperature on the permeation rates and the separation factors were studied. Permeation rates in VP and TDVP were found 0.03-0.41 kg/m(2) h and 0.10-0.45 kg/m(2) h, respectively. Separation factors were increased up to a certain content of zeolite (%15) than decreased, and higher separation factor was obtained in TDVP method (68.80) as compared to VP. Activation energy of permeation in VP was calculated to be 2.794 kcal/mol for 20 wt.% DMF solution.

Description

Keywords

Zeolite, Sodium Alginate, Vapor Permeation, Dimethylformamide

Journal or Series

DESALINATION AND WATER TREATMENT

WoS Q Value

N/A

Scopus Q Value

Q3

Volume

52

Issue

19-21

Citation