Bentonite-supported furfural-based Schiff base palladium nanoparticles: an efficient catalyst in treatment of water/wastewater pollutants

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dc.contributor.authorNasrollahzadeh, Mahmoud
dc.contributor.authorBaran, Talat
dc.contributor.authorSajjadi, Mohaddeseh
dc.contributor.authorYılmaz Baran, Nuray
dc.contributor.authorShokouhimehr, Mohammadreza
dc.date.accessioned2020-09-09T10:06:50Z
dc.date.available2020-09-09T10:06:50Z
dc.date.issued2020
dc.departmentSabire Yazıcı Fen Edebiyat Fakültesi
dc.description*Baran, Talat ( Aksaray, Yazar ) *Yılmaz Baran, Nuray ( Aksaray, Yazar )
dc.description.abstractThis study reports a versatile process for the fabrication of palladium nanoparticles (Pd NPs) stabilized on Schiff base modified Unye bentonite with a coordination performance of furfural ligand (UN-Fur@PdNPs) as a promising nanocatalyst in the reduction of organic/inorganic pollutants. APTES ((3-aminopropyl)triethoxysilane)-modified UN-Fur@PdNPs has been synthesized via a facile, multi-step procedure without any additional stabilizing/reducing agents. The characterization of UN-Fur@PdNPs sample was carried out by FTIR, XRD, EDS, elemental mapping, STEM, TEM, HRTEM, and TG/DTG analyses which indicate the formation of Pd NPs (~ 10 nm) on the surface of UN-Fur. The catalytic activity/stability of the as-prepared nanocatalyst has also been assessed in the reduction of 4-nitrophenol (4-NP), Congo Red (CR), Methylene Blue (MB), and Methyl Orange (MO) dyes by NaBH4 (sodium borohydride) and chromium [Cr(VI)] by HCOOH (formic acid) in water. Catalytic efficiency retention has also been obtained after eight cycles. UN-Fur@PdNPs showed excellent catalytic performance and high stability/sustainability in the reduction of all five targeted organic/inorganic pollutants.
dc.identifier.doi10.1007/s10854-020-03839-0
dc.identifier.endpage12871en_US
dc.identifier.issn0957-4522
dc.identifier.issue15en_US
dc.identifier.scopusqualityQ2
dc.identifier.startpage12856en_US
dc.identifier.urihttps:/dx.doi.org/10.1007/s10854-020-03839-0
dc.identifier.urihttps://hdl.handle.net/20.500.12451/7670
dc.identifier.volume31en_US
dc.identifier.wosWOS:000545056900001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSpringer
dc.relation.ispartofJournal of Materials Science: Materials in Electronics
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectAldehydes
dc.subjectAromatic Compounds
dc.subjectAzo Dyes
dc.subjectBentonite
dc.subjectCatalyst Activity
dc.titleBentonite-supported furfural-based Schiff base palladium nanoparticles: an efficient catalyst in treatment of water/wastewater pollutants
dc.typeArticle

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