Crystal structure of trans-diaquabis(nicotinamide-?N 1)bis(4-nitrobenzoato-?O)manganese(II)

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dc.authoridHokelek, Tuncer -- 0000-0002-8602-4382; Ozcelik, Nefise -- 0000-0002-6972-1071;
dc.contributor.authorAşkın, Gülçin Şefiye
dc.contributor.authorNecefoğlu, Hacali
dc.contributor.authorTonbul, Ali Murat
dc.contributor.authorDilek Özçelik, Nefise
dc.contributor.authorHökelek, Tuncer
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T09:18:25Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T09:18:25Z
dc.date.issued2016
dc.departmentFen-Edebiyat Fakültesi
dc.description.abstractThe asymmetric unit of the title compound, [Mn(C7H4NO4)(2)(C6H6N2O)(2)(H2O)(2)], contains one Mn-II atom, one 4-nitrobenzoate (NB) anion, one nicotinamide (NA) ligand and one water molecule; NA and NB each act as a monodentate ligand. The Mn-II atom, lying on an inversion centre, is coordinated by four O atoms and two pyridine N atoms in a distorted octahedral geometry. The water molecules are hydrogen bonded to the carboxylate O atoms. The dihedral angle between the carboxylate group and the adjacent benzene ring is 24.4 (3)degrees, while the benzene and pyridine rings are oriented at a dihedral angle of 86.63 (11)degrees. In the crystal, O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds link the molecules, forming a layer parallel to the ab plane. The layers are further linked via weak C-H center dot center dot center dot O hydrogen bonds, a pi-pi stacking interaction [centroid-centroid distance = 3.868 (2) angstrom] and a weak C-H center dot center dot center dot pi interaction, resulting in a three-dimensional network.
dc.description.sponsorshipAksaray University; Science and Technology Application and Research Center, Aksaray, Turkey [2010K120480]
dc.description.sponsorshipThe authors acknowledge the Aksaray University, Science and Technology Application and Research Center, Aksaray, Turkey, for the use of the Bruker SMART BREEZE CCD diffractometer (purchased under grant No. 2010K120480 of the State of Planning Organization).
dc.identifier.doi10.1107/S2056989016005612
dc.identifier.endpage+en_US
dc.identifier.issn2056-9890
dc.identifier.pmid27308012
dc.identifier.scopusqualityQ3
dc.identifier.startpage656en_US
dc.identifier.urihttps://doi.org/10.1107/S2056989016005612
dc.identifier.urihttps://hdl.handle.net/20.500.12451/4876
dc.identifier.volume72en_US
dc.identifier.wosWOS:000375489100014
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoen
dc.publisherInternational Union of Crystallography
dc.relation.ispartofActa Crystallographica Section E
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectCrystal Structure
dc.subjectManganese(II)
dc.subjectNicotinamide
dc.subject4-Nitrobenzoic Acid
dc.subjectTransition Metal Complex
dc.titleCrystal structure of trans-diaquabis(nicotinamide-?N 1)bis(4-nitrobenzoato-?O)manganese(II)
dc.typeArticle

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