Comparison of randomly-oriented ZnO nanorods and butterfly-type ZnO nanorod bundles for toluidine blue photocatalytic degradation

dc.contributor.authorÇakır, Alişah Çağatay
dc.contributor.authorGüloğlu, Pınar
dc.contributor.authorBilgin, Melayib
dc.contributor.authorErten Ela, Şule
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T08:23:23Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T08:23:23Z
dc.date.issued2012
dc.departmentMühendislik Fakültesi
dc.description.abstractThis paper is devoted to the decontamination of wastewater using ZnO nanostructures. The photocatalytic degradation of aqueous solution of a commercial dye, toluidine blue (TBO), has been investigated with two different kinds of ZnO nanostructures comprising butterfly-type ZnO nanorods and randomly-oriented ZnO nanorods. In order to be able to compare the photocatalytic efficiency, ZnO photocatalysts with two different crystalline structures are prepared by using different precursors but operating same microwave-assisted method. Butterfly-type ZnO nanorods are synthesized by using surfactants. Randomly-oriented ZnO nanorods with environmentally-friendly method are obtained without using any base and surfactant. The two different kinds of ZnO photocatalysts are characterized by X-Ray diffraction (XRD), scanning electron microscopy (SEM), UV-Vis absorption spectrum. The effects of pH, ZnO catalyst dosage and TBO initial dye concentration are tested experimentally for photocatalytic degradation. After 90 minutes reaction time, the decolorization efficiency of the TBO achieved 85.20% for butterfly-type ZnO nanorods and 77.20% for randomly-oriented ZnO nanorods. Additionally, under the same optimum conditions of pH=11, [ZnO]= 1g-ZnO L -1, [TBO]= 108 mg TBO L -1, Total Organic Carbon (TOC) removal efficiencies are obtained 56.70% and 40.80% for butterfly-type ZnO nanorods and randomlyoriented ZnO nanorods, respectively.
dc.identifier.endpage237en_US
dc.identifier.issn1454-4164
dc.identifier.issue03.Apren_US
dc.identifier.scopusqualityQ4
dc.identifier.startpage230en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12451/2756
dc.identifier.volume14en_US
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.relation.ispartofJournal of Optoelectronics and Advanced Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectDecontamination of Water
dc.subjectPhotocatalysis
dc.subjectPhotodegradation
dc.subjectTotal organic Carbon Removal
dc.subjectZnO Nanorod
dc.titleComparison of randomly-oriented ZnO nanorods and butterfly-type ZnO nanorod bundles for toluidine blue photocatalytic degradation
dc.typeArticle

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