Browsing by Author "Narayanan, Ramakirushnan Suriya"

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Reactivity enhancement of a diphosphene by reversible N-heterocyclic carbene coordination

Dhara, Debabrata; Kalita, Pankaj; Mondal, Subhadip; Narayanan, Ramakirushnan Suriya; Mote, Kaustubh R.; Huch, Volker; Zimmer, Michael; Yıldız, Cem Burak; Scheschkewitz, David; Chandrasekhar, Vadapalli; Jana, Ankul (Royal Society of Chemistry, 2018)

Diphosphene TerMesP = PTerMes (1; TerMes = 2,6-Mes2C6H3; Mes = 2,4,6-Me3C6H2) and NHCMe42 (NHCMe4 = 1,3,4,5-tetramethylimidazol-2-ylidene) exist in an equilibrium mixture with the NHCMe4-coordinated diphosphene 3. While ...