The effects of temperature on transport phenomena in phosphoric acid doped polybenzimidazole polymer electrolyte membrane fuel cell

dc.authoridCELIK, MUHAMMET -- 0000-0001-8978-4814;
dc.contributor.authorElden, Gülşah
dc.contributor.authorÇelik, Muhammet
dc.contributor.authorGenç, Gamze
dc.contributor.authorYapıcı, Hüseyin
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-29T19:27:43Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-29T19:27:43Z
dc.date.issued2016
dc.departmentMühendislik Fakültesi
dc.description.abstractAn energy analysis for the H3PO4 (phosphoric acid) doped PBI (polybenzimidazole) polymer electrolyte membrane fuel cell depending on the operating temperature is aimed in this study. In line with this aim, the relation of heat sources from electrochemical reaction, ionic and electronic current with the cell operating temperature is analyzed in detail for both anode catalyst layer and cathode catalyst layer. In addition, effect of the cell operating temperature on species and charge in the fuel cell is indicated. For this analysis, a single phase and two dimensional numerical model is developed with the help of COMSOL Multiphysics 4.2a software under the conditions of the different cell operating temperatures (from 120 to 180 degrees C stepping by 20 degrees C) and a constant acid doping level (6.75 RPU H3PO4/PBI). The results bring out that the irreversible and reversible entropic heat sources are more dominant than the joule heating source and the heat source by conduction at the cathode catalyst layer. The molar concentrations of all species through all layers are also presented. (C) 2016 Elsevier Ltd. All rights reserved.
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [111M071]
dc.description.sponsorshipThe authors would like to thank the Scientific and Technological Research Council of Turkey (TUBITAK) for funding supported by project coded 111M071.
dc.identifier.doi10.1016/j.energy.2016.02.137
dc.identifier.endpage783en_US
dc.identifier.issn0360-5442
dc.identifier.issn1873-6785
dc.identifier.scopusqualityQ1
dc.identifier.startpage772en_US
dc.identifier.urihttps://doi.org/10.1016/j.energy.2016.02.137
dc.identifier.urihttps://hdl.handle.net/20.500.12451/5918
dc.identifier.volume103en_US
dc.identifier.wosWOS:000376800200066
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherPergamon-Elsevier Science Ltd
dc.relation.ispartofEnergy
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectHigh Temperature PEM Fuel Cell
dc.subjectPhosphoric Acid Doped Polybenzimidazole
dc.subjectHeat Transport
dc.subjectMass Transport
dc.subjectCharge Transport
dc.titleThe effects of temperature on transport phenomena in phosphoric acid doped polybenzimidazole polymer electrolyte membrane fuel cell
dc.typeArticle

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