Ring-opening mechanism of lithium bromosilacyclopropylidenoids to silaallenes
| dc.authorid | Azizoglu, Akin -- 0000-0002-5098-1842; Yildiz, Cem Burak -- 0000-0002-0424-4673 | |
| dc.contributor.author | Azizoğlu, Akın | |
| dc.contributor.author | Yıldız, Cem Burak | |
| dc.date.accessioned | 13.07.201910:50:10 | |
| dc.date.accessioned | 2019-07-29T19:26:59Z | |
| dc.date.available | 13.07.201910:50:10 | |
| dc.date.available | 2019-07-29T19:26:59Z | |
| dc.date.issued | 2010 | |
| dc.department | Teknik Bilimler Meslek Yüksekokulu | |
| dc.description.abstract | Density functional theory and ab initio quantum mechanical calculations elucidated the ring opening reactions of 1 bromo 1 lithiosilirane (3) and 2 bromo 2 lithiosilirane (4) to 2 silallene (6) and 1 silaallene (7) respectively The ring opening of 3 to 6 can proceed in a stepwise fashion with the intermediacy of a free silacyclopropylidene (9) Here a high energy barrier needs to be overcome in order to open the silacyclopropylidene ring and to generate 6 On the contrary the ring opening of 4 to 7 can occur in a concerted fashion | |
| dc.description.sponsorship | Scientific and Technical Research Council of Turkey (TUBITAK) | |
| dc.description.sponsorship | We thank the Scientific and Technical Research Council of Turkey (TUBITAK) for generous financial support We are also grateful to the reviewers for their helpful comments | |
| dc.identifier.doi | 10.1021/om100868b | |
| dc.identifier.endpage | 6743 | en_US |
| dc.identifier.issn | 0276-7333 | |
| dc.identifier.issue | 24 | en_US |
| dc.identifier.scopusquality | Q2 | |
| dc.identifier.startpage | 6739 | en_US |
| dc.identifier.uri | https://doi.org/10.1021/om100868b | |
| dc.identifier.uri | https://hdl.handle.net/20.500.12451/5762 | |
| dc.identifier.volume | 29 | en_US |
| dc.identifier.wos | WOS:000285373100017 | |
| dc.identifier.wosquality | N/A | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.relation.ispartof | Organometallics | |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
| dc.rights | info:eu-repo/semantics/closedAccess | |
| dc.title | Ring-opening mechanism of lithium bromosilacyclopropylidenoids to silaallenes | |
| dc.type | Article |
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