Comparative assessment of various chlorine family thermochemical cycles for hydrogen production

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Tarih

2016

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Pergamon-Elsevier Science

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

This study deals with a comparative assessment of various chlorine family cycles, namely copper chlorine (CuCl), magnesium-chlorine (MgCl), iron-chlorine (Fe-Cl) and vanadium-chlorine (V-Cl) cycles, which are driven by heat and/or electricity. Hydrogen production through thermochemical and/or hybrid cycles can play a significant role in reducing greenhouse gas emissions and hence offering opportunities for better environment and sustainability. In this paper, we conduct energy and exergy analyses of the VCl cycle and examine both energy and exergy efficiencies of the cycle. We also undertake a parametric study to investigate how the overall cycle performance is affected by changing the reference environment temperature and cycle operating conditions. The performance of VCl cycle are evaluated and compared with CuCl, MgCl and FeCl cycles. Furthermore, these cycles are discussed and compared with each other through their advantages and challenges. As a result, VCl cycle offers a good potential due to its high efficiency over 40% based on a complete reaction. In this regard, VCl cycle appears to be one of the most promising low temperature cycles. It may, therefore, compete with other low temperature cycles such as copper-chlorine. (

Açıklama

6th International Conference on Progress in Hydrogen Production and Applications (ICH2P) -- MAY 03-06, 2015 -- Oshawa, CANADA
WOS:000376695800010

Anahtar Kelimeler

Cu-Cl, Mg-Cl, Fe-Cl, V-Cl, Thermochemical, Hydrogen

Kaynak

International Journal of Hydrogen Energy

WoS Q Değeri

N/A

Scopus Q Değeri

Q1

Cilt

41

Sayı

19

Künye