Synthesis, structural characterization and microbial activity of 2D Ag(I)-5-aminoisophthalate coordination polymer with a new coordination mode
Yükleniyor...
Dosyalar
Tarih
2015
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, a novel polynuclear Ag(I)-5-aminoisophthalate complex [Ag(µ<inf>4</inf>-Haip)]<inf>n</inf> (1) (H<inf>2</inf>aip = 5-aminoisophthalic acid) has been synthesized. The molecular structure of this complex has been determined by the single crystal X-ray diffraction. The two-dimensional polynuclear complex is crystallized in the triclinic crystal system with space group P-1. The Ag(I) ion is four-coordinated by three carboxylate oxygen atoms of three different Haip ligands and one nitrogen atom in a distorted tetrahedral geometry. Furthermore, a novel coordination mode has shown by H<inf>2</inf>aip. This complex exhibits photoluminescence in the solid state at room temperature. Antimicrobial activity of complex was evaluated by the agar diffusion method. The complex showed antimicrobial activity against tested microorganism strains (Gram positive, gram negative bacteria, clinic isolate yeast and mold). Moreover this complex showed particularly high antifungal activity against yeast and mold. © 2015 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
5-Aminoisophthalic Acid, Antimicrobial Activity, Clinic İsolates, Photoluminescence, Silver(I) Complex
Kaynak
Journal of Molecular Structure
WoS Q Değeri
Scopus Q Değeri
Q1
Cilt
1099
