Crystal structure of diaquabis(N,N-diethylnicotinamide- kN1)bis(2,4,6-trimethylbenzoato-kO1)cobalt(II)

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dc.authoridHokelek, Tuncer -- 0000-0002-8602-4382
dc.contributor.authorAş?ın, Gülçin Şefiye
dc.contributor.authorNecefo?lu, Hacali
dc.contributor.authorÖzkaya, Safiye
dc.contributor.authorÇelik, Raziye Çatak
dc.contributor.authorHökelek, Tuncer
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T09:18:26Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T09:18:26Z
dc.date.issued2016
dc.departmentBilimsel ve Teknolojik Uygulama ve Araştırma Merkezi
dc.description.abstractThe centrosymmetric molecule in the monomeric title cobalt complex, [Co(C10H11O2)(2) (C10H14N2O)(2)(H2O)(2)], contains two water molecules, two 2,4,6-trimethylbenzoate (TMB) ligands and two diethylnicotinamide (DENA) ligands. All ligands coordinate to the Co-II atom in a monodentate fashion. The four O atoms around the Co-II atom form a slightly distorted square-planar arrangement, with the distorted octahedral coordination sphere completed by two pyridine N atoms of the DENA ligands. The dihedral angle between the planar carboxylate group and the adjacent benzene ring is 84.2 (4)degrees, while the benzene and pyridine rings are oriented at a dihedral angle of 38.87 (10)degrees. The water molecules exhibit both intramolecular (to the non-coordinating carboxylate O atom) and intermolecular (to the amide carbonyl O atom) O-H center dot center dot center dot O hydrogen bonds. The latter lead to the formation of layers parallel to (100), enclosing R-4(4) (32) ring motifs. These layers are further linked via weak C-H center dot center dot center dot O hydrogen bonds, resulting in a three-dimensional network. One of the two ethyl groups of the DENA ligand is disordered over two sets of sites with an occupancy ratio of 0.490 (13): 0.510 (13).
dc.identifier.doi10.1107/S2056989016004059
dc.identifier.endpage+en_US
dc.identifier.issn2056-9890
dc.identifier.pmid27375874
dc.identifier.scopusqualityQ3
dc.identifier.startpage498en_US
dc.identifier.urihttps://doi.org/10.1107/S2056989016004059
dc.identifier.urihttps://hdl.handle.net/20.500.12451/4878
dc.identifier.volume72en_US
dc.identifier.wosWOS:000374651100019
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherINT Union Crystallography
dc.relation.ispartofACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectCrystal Structure
dc.subjectCobalt(II)
dc.subjectTransition metal Complexes of Benzoic Acid and Nicotinamide Derivatives
dc.titleCrystal structure of diaquabis(N,N-diethylnicotinamide- kN1)bis(2,4,6-trimethylbenzoato-kO1)cobalt(II)
dc.typeArticle

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