The effect of polyurethane and carnauba wax on the mechanical and physicochemical properties of acrylonitrile butadiene nitrile rubber coating working gloves

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dc.authoridDusunceli, Necmi -- 0000-0002-2841-7882
dc.contributor.authorDüşünceli, Necmi
dc.contributor.authorAkyüz, Lalehan
dc.contributor.authorŞahin, Necmettin
dc.contributor.authorDuru, Hatice
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T09:16:29Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T09:16:29Z
dc.date.issued2019
dc.departmentMühendislik Fakültesi
dc.description.abstractIn this study, the effect of polyurethane (PU) and carnauba wax (CW) on the mechanical and physicochemical properties of acrylonitrile butadiene nitrile rubber coating gloves was investigated. Thermal decomposition and morphological characterizations were carried out using Thermogravimetric analysis (TGA) and Scanning Electron Microscopy (SEM), respectively. Fourier-transform infrared spectroscopy (FTIR) analysis was done to determine the chemical interactions between NBR and PU in the polymer matrix. After the vulcanization of NBR, including PU and CW, thermal stability was increased. The spectrums of FTIR showed that carboxyl groups of NBR were linked to the PU to form stable complexes between polymeric chains via H-bonding. SEM images showed that because CW acted as a dispersant for the colloidal particles, the surface appeared smooth compared with the non-containing PU/CW samples. Tensile and tear strength and abrasion resistance tests were conducted using the specimens of vulcanized NBR including PU/CW under uniaxial loading. Test specimens were prepared using hydraulic mold according to EN 388 standards. Cross-head speeds were chosen as 100 mm min(-1). The chemical and morphological changes due to PU/CW had no significant effects on the macro-mechanical responses of the tensile and tear strength. However, it was obviously determined that the abrasion resistance was enhanced by the increase in the amount of CW.
dc.description.sponsorshipT. C. Small and Medium Business Development and Support Administration
dc.description.sponsorshipThe author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This work was financially supported by T. C. Small and Medium Business Development and Support Administration.
dc.identifier.doi10.1177/0095244318768650
dc.identifier.endpage51en_US
dc.identifier.issn0095-2443
dc.identifier.issn1530-8006
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ3
dc.identifier.startpage36en_US
dc.identifier.urihttps://doi.org/10.1177/0095244318768650
dc.identifier.urihttps://hdl.handle.net/20.500.12451/4603
dc.identifier.volume51en_US
dc.identifier.wosWOS:000457635600003
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherSage Publications Ltd
dc.relation.ispartofJournal of Elastomers and Plastics
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectNBR Gloves
dc.subjectPhysicochemical c-Characterization
dc.subjectMechanical Properties
dc.subjectTearing
dc.subjectAbrasion
dc.subjectSEM
dc.subjectFourier-transform Infrared Spectroscopy
dc.titleThe effect of polyurethane and carnauba wax on the mechanical and physicochemical properties of acrylonitrile butadiene nitrile rubber coating working gloves
dc.typeArticle

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