Catena-Poly[[aquabis(3-chlorobenzoato-K2 O,O')cadmium]-µ-N,N-diethylnicotinamide-K2 N 1:O]

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dc.contributor.authorBozkurt, Nihat
dc.contributor.authorTunç, Tuncay
dc.contributor.authorÇaylak Delibaş, Nagihan
dc.contributor.authorNecefoglu, Hacali
dc.contributor.authorHökelek, Tuncer
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T08:22:55Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T08:22:55Z
dc.date.issued2013
dc.departmentEğitim Fakültesi
dc.description.abstractIn the crystal of the title CdII polymeric complex, [Cd(C7H4ClO2)2(C10H14N2O)(H2O)] n , the CdII cation is chelated by two chlorobenzoate anions and coordinated by two N,N-diethylnicotinamide (DENA) ligands and one water molecule in a distorted NO6 pentagonal-bipyramidal geometry. The CdII cations are bridged by the pyridine N atom and carbonyl O atom of the DENA ligand to form a polymeric chain running along the b axis. Intermolecular O - H?O hydrogen bonds between coordinating water molecules and carboxylate groups link adjacent chains into layers parallel to the bc plane. ?-? contacts between benzene rings [shortest centroid-centroid distance = 3.912 (2) Å] further stabilizes the crystal structure. In the molecule, weak C - H?O hydrogen bonds occur between the pyridine ring and carboxylate groups; the dihedral angles between the carboxylate groups and adjacent benzene rings are 4.6 (3) and 12.8 (3)°, while the benzene rings are oriented at a dihedral angle of 1.89 (13)°.
dc.identifier.doi10.1107/S160053681301965X
dc.identifier.endpage467en_US
dc.identifier.issn1600-5368
dc.identifier.issue8en_US
dc.identifier.scopusqualityN/A
dc.identifier.startpage466en_US
dc.identifier.urihttps://dx.doi.org/10.1107/S160053681301965X
dc.identifier.urihttps://hdl.handle.net/20.500.12451/2671
dc.identifier.volume69en_US
dc.indekslendigikaynakScopus
dc.language.isoen
dc.relation.ispartofActa Crystallographica Section E: Structure Reports Online
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectData-to-Parameter Ratio = 20.0
dc.subjectMean?(C - C) = 0.006 A °
dc.subjectRfactor = 0.046
dc.subjectSingle-Crystal X-ray Study
dc.subjectT = 296 K
dc.subjectwRfactor = 0.093
dc.titleCatena-Poly[[aquabis(3-chlorobenzoato-K2 O,O')cadmium]-µ-N,N-diethylnicotinamide-K2 N 1:O]
dc.typeArticle

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