Simultaneous electrocatalytic reduction of dinitrogen and carbon dioxide on conducting polymer electrodes

Basit Öğe Kaydı
dc.contributor.authorBalun Kayan, Didem
dc.contributor.authorKöleli, Fatih
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-29T19:27:24Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-29T19:27:24Z
dc.date.issued2016
dc.departmentFen-Edebiyat Fakültesi
dc.description.abstractThe conversion of carbon dioxide with nitrogen containing compounds into valuable materials consistings of C-N bond is a very attractive research area due to today's energy requirements. The simultaneous electrocatalytic reduction of carbon dioxide and dinitrogen was investigated at 60 bar (30 bar N-2+30 bar CO2) in this study. The electrochemical reduction was achieved on polyaniline (PAni) and polypyrrole (PPy) coated platinum electrodes at -0.165V, the lowest possible overpotentials, known in the literature. The main products from the CO2 and N-2 reduction were ammonia, urea and formic acid. The electrochemical reduction performed in an aqueous 0.1 M Li2SO4/0.03 MH+ solution was characterized by using cyclic voltammetry, potentiostatic electrolysis and Tafel diagrams in order to analyze the polymer selectivity as well as its reactivity as a function of the applied potential. Hence, CO2 and N-2 were converted into value added chemicals, which included urea; an important raw material for the chemical industry with high nitrogen content.
dc.description.sponsorshipMersin University Research Foundation [BAP-FBE KB (DBK) 2006-3 DR]; Scientific and Technological Research Council of Turkey [TUBITAK-104T353]
dc.description.sponsorshipThe authors gratefully acknowledge the Mersin University Research Foundation (BAP-FBE KB (DBK) 2006-3 DR) and The Scientific and Technological Research Council of Turkey (TUBITAK-104T353) for the financial support.
dc.identifier.doi10.1016/j.apcatb.2015.07.045
dc.identifier.endpage93en_US
dc.identifier.issn0926-3373
dc.identifier.issn1873-3883
dc.identifier.startpage88en_US
dc.identifier.urihttps://doi.org/10.1016/j.apcatb.2015.07.045
dc.identifier.urihttps://hdl.handle.net/20.500.12451/5855
dc.identifier.volume181en_US
dc.identifier.wosWOS:000364256000010
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.language.isoen
dc.publisherELSEVIER SCIENCE BV
dc.relation.ispartofAPPLIED CATALYSIS B-ENVIRONMENTAL
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/embargoedAccess
dc.subjectN-2-Reduction
dc.subjectCO2-Reduction
dc.subjectConducting Polymer
dc.subjectUrea Formation
dc.titleSimultaneous electrocatalytic reduction of dinitrogen and carbon dioxide on conducting polymer electrodes
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
balun kayan-didem-2016.pdf
Boyut:
1.42 MB
Biçim:
Adobe Portable Document Format
Açıklama:
Tam Metin / Full Text
İndir

Koleksiyon

Makale Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu