Cu(II) and Ni(II) 4-cyanobenzoate complexes with nicotinamide: Synthesis, spectral, structural and optical characterization and thermal behavior

dc.authoridHokelek, Tuncer -- 0000-0002-8602-4382; Ozturkkan, Fureya Elif -- 0000-0001-6376-4161;
dc.contributor.authorÖzbek, Füreya Elif
dc.contributor.authorSertçelik, Mustafa
dc.contributor.authorYüksek, Mustafa
dc.contributor.authorNecefoğlu, Hacali
dc.contributor.authorÇelik, Raziye Çatak
dc.contributor.authorNayır, Gamze Yılmaz
dc.contributor.authorHökelek, Tuncer
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T09:17:40Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T09:17:40Z
dc.date.issued2017
dc.departmentBilimsel ve Teknolojik Uygulama ve Araştırma Merkezi
dc.description.abstractTwo new copper(II) and nickel(II) complexes [M(NC-C6H4COO)2(C6H6N2O)(2)(H20)(2)] (where M:Cu and Ni) have been synthesized and characterized by elemental analysis, FT-IR and UV Vis spectroscopy, spectroscopic ellipsometer (SE), X-ray crystallography, thermal analysis and molar conductivity. X-ray measurements showed that both of the complexes crystallized in triclinic system with the space group P-1. The isostructure complexes have distorted octahedral geometry around the metal atom center. In both of the crystal structures, the metal atoms are coordinated by two nitrogen atoms from two different nicotinamide ligands, two carboxyl oxygen atoms from two different 4-cyanobenzoate anions and two oxygen atoms from two different water molecules. From the linear absorption spectra and spectroscopic ellipsometer measurements, it was observed that these complexes showed different optical behaviors.
dc.description.sponsorshipKafkas University Research Fund [2016-FM-49]
dc.description.sponsorshipThe authors thank the Kafkas University Research Fund for financial support under Grant No. 2016-FM-49.
dc.identifier.doi10.1016/j.molstruc.2017.08.074
dc.identifier.endpage117en_US
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopusqualityQ1
dc.identifier.startpage112en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2017.08.074
dc.identifier.urihttps://hdl.handle.net/20.500.12451/4780
dc.identifier.volume1150en_US
dc.identifier.wosWOS:000413387400014
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Bv.
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subject4-Cyanobenzoic Acid
dc.subjectCu(II)
dc.subjectNi(II)
dc.subjectOptical Characterization
dc.subjectNicotinamide
dc.subjectXRD
dc.titleCu(II) and Ni(II) 4-cyanobenzoate complexes with nicotinamide: Synthesis, spectral, structural and optical characterization and thermal behavior
dc.typeArticle

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