Reactivity of NHC/diphosphene-coordinated Au(i)-hydride

Basit Öğe Kaydı
dc.contributor.authorDhara, Debabrata
dc.contributor.authorScheschkewitz, David
dc.contributor.authorChandrasekhar, Vadapalli
dc.contributor.authorYıldız, Cem B.
dc.contributor.authorJana, Anukul
dc.date.accessioned2021-07-02T13:13:37Z
dc.date.available2021-07-02T13:13:37Z
dc.date.issued2021
dc.departmentTeknik Bilimler Meslek Yüksekokulu
dc.description*Yıldız, Cem B. ( Aksaray, Yazar )
dc.description.abstractWe report the reactivity of isolable Au(i)-hydride stabilized by an NHC-coordinated diphosphene towards substrates containing C-C and N-N multiple bonds (NHC = N-heterocyclcic carbene). Reactions with dimethyl acetylenedicarboxylate and azobenzene lead to a trans-addition of the Au(i)-H across the C-C triple bond and the N-N double bond, respectively. In contrast, the reaction with ethyl diazoacetate affords a gold(i)-hydrazonide as the 1,1-addition product to the terminal nitrogen atom. With phenyl acetylene, the corresponding Au(i)-alkynyl complex is obtained under the elimination of dihydrogen. Strikingly, diphosphene-containing Au(i)-hydride is more reactive-affording different products in some cases-than a related NHC-stabilized Au(i)-hydride without the mediating diphosphene moiety.
dc.identifier.doi10.1039/d0cc05461e
dc.identifier.endpage812en_US
dc.identifier.issue6en_US
dc.identifier.pmid33367425
dc.identifier.scopusqualityQ1
dc.identifier.startpage809en_US
dc.identifier.urihttps:/dx.doi.org/10.1039/d0cc05461e
dc.identifier.urihttps://hdl.handle.net/20.500.12451/8299
dc.identifier.volume57en_US
dc.identifier.wosWOS:000611726300025
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.relation.ispartofChemical Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectReactivity of NHC/diphosphene-coordinated Au(i)-hydride
dc.titleReactivity of NHC/diphosphene-coordinated Au(i)-hydride
dc.typeArticle

Dosyalar

Lisans paketi
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
license.txt
Boyut:
1.44 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama:
İndir

Koleksiyon

Makale Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu