Catena-Poly[[diaquabis(4-formylbenzoato-KO 1)copper(II)]- µ-pyrazine-K2 N:N']

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dc.contributor.authorÇelik, Fatih
dc.contributor.authorDilek, Nefise
dc.contributor.authorÇaylak Delibaş, Nagihan
dc.contributor.authorNecefoğlu, Hacali
dc.contributor.authorHökelek, Tuncer
dc.date.accessioned13.07.201910:50:10
dc.date.accessioned2019-07-16T08:22:38Z
dc.date.available13.07.201910:50:10
dc.date.available2019-07-16T08:22:38Z
dc.date.issued2014
dc.departmentSabire Yazıcı Fen Edebiyat Fakültesi
dc.description.abstractIn the title polymeric compound, [Cu(C8H5O 3)2(C4H4N2)(H2O) 2]n , the CuII atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination sphere. In the equatorial plane, it is coordinated by two carboxylate O atoms of two symmetry-related monodentate formylbenzoate anions and by two N atoms of the bridging pyrazine ligand, which is bisected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water molecules. In the formylbenzoate anion, the carboxylate group is twisted away from the attached benzene ring by 6.2(2)°, while the benzene and pyrazine rings are oriented at a dihedral angle of 68.91(8)°. The pyrazine ligands bridge the Cu II cations, forming polymeric chains running along the b-axis direction. Strong intramolecular O-H?O hydrogen bonds link the water molecules to the carboxylate O atoms. In the crystal, O-Hwater?Owater hydrogen bonds link adjacent chains into layers parallel to the bc plane. The layers are linked via C-Hpyrazine?Oformyl hydrogen bonds, forming a three-dimensional network. There are also weak C-H?? interactions present.
dc.identifier.doi10.1107/S1600536813032297
dc.identifier.endpagem5en_US
dc.identifier.issn1600-5368
dc.identifier.issue1en_US
dc.identifier.scopusqualityN/A
dc.identifier.startpagem4en_US
dc.identifier.urihttps://dx.doi.org/10.1107/S1600536813032297
dc.identifier.urihttps://hdl.handle.net/20.500.12451/2611
dc.identifier.volume70en_US
dc.indekslendigikaynakScopus
dc.language.isoen
dc.relation.ispartofActa Crystallographica Section E: Structure Reports Online
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.titleCatena-Poly[[diaquabis(4-formylbenzoato-KO 1)copper(II)]- µ-pyrazine-K2 N:N']
dc.typeArticle

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